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-Dominant- [34]
3 years ago
9

For the reaction CO+2H2=CH3OH at 700 K, equilibrium concentrations are [H2]=0.072 M, [CO]= 0.020M, and [CH3OH]= 0.030 M. Calcula

te K
Chemistry
1 answer:
bekas [8.4K]3 years ago
3 0

The balanced equation for the reaction is

CO(g) + 2H₂(g) ⇄ CH₃OH(g)

 

The given concentrations are at equilibrium state. Hence we can use them directly in calculation with the expression for the equilibrium constant, k. expression for k can be written as

   k = [CH₃OH(g)] / [CO(g)] [H₂<span>(g) ]²

</span>[H₂<span>]=0.072 M
[CO]= 0.020M
[CH</span>₃OH]= 0.030 M

 

From substitution,

   k = 0.030 M / 0.020 M x (0.072 M)²

   k = 289.35 M⁻²

<span>
Hence, equilibrium constant for the given reaction at 700 K is 289.35 M</span>⁻².

<span> </span>

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How many grams of chlorine gas are present in a 150. liter cylinder of chlorine held at a pressure of 1.00 atm and 0. °C? Group
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Answer:

474 grams of chlorine gas are present in a 150 liter cylinder of chlorine held at a pressure of 1.00 atm and 0 °C

Explanation:

An ideal gas is a theoretical gas that is considered to be composed of randomly moving point particles that do not interact with each other. Gases in general are ideal when they are at high temperatures and low pressures.

The pressure, P, the temperature, T, and the volume, V, of an ideal gas, are related by a simple formula called the ideal gas law:  

P*V = n*R*T

where P is the gas pressure, V is the volume that occupies, T is its temperature, R is the ideal gas constant, and n is the number of moles of the gas.

In this case:

  • P= 1.00 atm
  • V= 150 L
  • n= ?
  • R= 0.082 \frac{atm*L}{mol*K}
  • T= 0 C= 273 K

Replacing:

1.00 atm* 150 L= n*0.08206 \frac{atm*L}{mol*K} *273 K

Solving:

n=\frac{1.00 atm* 150 L}{0.08206 \frac{atm*L}{mol*K}*273 K}

n= 6.69 moles

Being Cl= 35.45 g/mole, the molar mass of chlorine gas is:

Cl₂=2*35.45 g/mole= 70.9 g/mole

So if 1 mole has 70.9 grams, 6.69 moles of the gas, how much mass does it have?

mass=\frac{6.69 moles*70.9 grams}{1 mole}

mass= 474.321 grams ≅ 474 grams

<u><em>474 grams of chlorine gas are present in a 150 liter cylinder of chlorine held at a pressure of 1.00 atm and 0 °C</em></u>

4 0
3 years ago
1. A sample of polystyrene is found to have a number-average molar mass of 89,440 g mol−1 . Neglecting contributions from end gr
Snowcat [4.5K]

Answer:

The weight-average molar mass of polystyrene is 134,160 g/mol.

Explanation:

Molar mass of the monomer styrene , C_8H_8, M=104 g/mol

Given , number average molar mass of the polymer , M'= 89,440 g/mol

Degree of polymerization = n

n=\frac{M'}{M}=\frac{89,440 g/mol}{104 g/mol}=860

The weight-average molar mass = M_{avg}=?

Molar mass dispersity is ratio of weight-average molar mass to the number average molar mass of the polymer.

\text{Molar mass dispersity}=\frac{M_{avg}}{M'}

1.5=\frac{M_{avg}}{89,440 g/mol}

M_{avg}=89,440 g/mol\times 1.5 = 134,160 g/mol

The weight-average molar mass of polystyrene is 134,160 g/mol.

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