Consider the reversible, elementary, gas phase reaction of A and B to form C occurring at 300 K in a variable volume (constant p
ressure) reactor with an initial volume of 1.0 L. For a reactant charge to the reactor of 1.0 mol of A, 2.0 mol of B, and no C, find the equilibrium conversion of A. Plot the composition in the reactor and the reactor volume as a function of time.
1 answer:
Complete Question
The complete question is shown on the first uploaded image
Answer:
The equilibrium conversion is 1.562 where lt denotes liter
The final pressure is 3895.94 Kpa
The plot of the composition of the reactor volume as a function of time is on the second uploaded image
Explanation:
The explanation is shown on the third , fourth and fifth images
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This question is incomplete, the complete question is;
An air-standard Diesel cycle engine operates as follows: The temperatures at the beginning and end of the compression stroke are 30 °C and 700 °C, respectively. The net work per cycle is 590.1 kJ/kg, and the heat transfer input per cycle is 925 kJ/kg. Determine the a) compression ratio, b) maximum temperature of the cycle, and c) the cutoff ratio, v3/v2.
Use the cold air standard assumptions.
Answer:
a) The compression ratio is 18.48
b) The maximum temperature of the cycle is 1893.4 K
c) The cutoff ratio, v₃/v₂ is 1.946
Explanation:
Given the data in the question;
Temperature at the start of a compression T₁ = 30°C = (30 + 273) = 303 K
Temperature at the end of a compression T₂ = 700°C = (700 + 273) = 973 K
Net work per cycle = 590.1 kJ/kg
Heat transfer input per cycle Qs = 925 kJ/kg
a) compression ratio;
As illustrated in the diagram below, 1 - 2 is adiabatic compression;
so,
Tγ = constant { For Air, γ = 1.4 }
hence;
⇒ V₁ / V₂ = T₂ / T₁
so we substitute
⇒ V₁ / V₂ = 973 K / 303 K
= 3.21122
= 18.4788 ≈ 18.48
Therefore, The compression ratio is 18.48
b) maximum temperature of the cycle
We know that for Air, Cp = 1.005 kJ/kgK
Now,
Heat transfer input per cycle Qs = Cp( T₃ - T₂ )
we substitute
925 = 1.005( T₃ - 700 )
( T₃ - 700 ) = 925 / 1.005
( T₃ - 700 ) = 920.398
T₃ = 920.398 + 700
T₃ = 1620.398 °C
T₃ = ( 1620.398 + 273 ) K
T₃ = 1893.396 K ≈ 1893.4 K
Therefore, The maximum temperature of the cycle is 1893.4 K
c) the cutoff ratio, v₃/v₂;
Since pressure is constant, V ∝ T
So,
cutoff ratio S = v₃ / v₂ = T₃ / T₂
we substitute
cutoff ratio S = 1893.396 K / 973 K
cutoff ratio S = 1.9459 ≈ 1.946
Therefore, the cutoff ratio, v₃/v₂ is 1.946
