The answer to your question is A <span>4.184 J</span>
As mentioned above, phosphoric acid has 3 pKa values, and after 3 ionization it gives 3 types of ions at different pKa values:
H₃PO₄(aq)
+ H₂O(l) ⇌ H₃O⁺(aq) + H₂PO₄⁻ (aq) pKₐ₁
<span>
</span>H₂PO₄⁻(aq) + H₂O(l) ⇌ H₃O⁺(aq) + HPO₄²⁻ (aq) pKₐ₂
HPO₄²⁻(aq) + H₂O(l) ⇌ H₃O⁺(aq) + PO₄³⁻ (aq) pKₐ₃
At the highest pKa value (12.4) of phosphoric acid, the last OH group will lose its hydrogen. On the picture I attached, it is shown required protonated form of phosphoric acid before reaction whose pKa value is 12.4.
It is a completely true statement that a <span>base increases the OH- ion concentration of water. The correct option among the two options that are given in the question is the first option. I hope that this is the answer that you were looking for and the answer has actually come to your desired help.</span>
Explanation:
As the charge of all electrons are equal, the repulsive force exerted by each of them is also going to be equal. So, as K has more electrons repulsing its valence electron than Na, it has greater electron shielding.