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True [87]
3 years ago
13

The gas phosphine (PH3) is used as a fumigant to protect stored grain and other durable produce from pests. Phosphine is generat

ed where it is to be used by adding water to aluminum phosphide or magnesium phosphide. Give formulas for these two phosphides.
Chemistry
2 answers:
Nezavi [6.7K]3 years ago
8 0
<span>The gas phosphine (PH3) is used as a fumigant to protect stored grain and other durable produce from pests. Phosphine is generated where it is to be used by adding water to aluminum phosphide or magnesium phosphide. Give formulas for these two phosphides.

</span>Al₂P₃ + 3H₂O → 3PH₃ + Al₂O₃
MgP + H₂O → PH₃ + MgO
horrorfan [7]3 years ago
7 0

1) Molecular formula for aluminium phospide is AlP. Aluminium has oxidation number +3 (metal from 13. group of periodic table) and phosphorus in phospides has oxidation number -3.

Aluminium phosphide is a highly toxic, solid inorganic compound.

2) Molecular formula for aluminium phospide is Mg₃P₂. Magnesium has oxidation number +2 (metal from 2. group of periodic table) and phosphorus in phospides has oxidation number -3.

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We use the MO diagram for a homonuclear diatomic species (since C and N are neighbours, we treat them as the "same").

The first two electrons contribute to bonding. The next two are anti-bonding.

The next six contribute to bonding, and the following six are anti-bonding.

So, if we start with CN+, which has 4+5-1 (8) valence electrons, we note that the first two electrons contribute to bonding, while the next two cancel this out; the next four contribute to bonding, so the bond order is 4/2 = 2.

If we add one more electron to get CN, there are now 5 bonding electrons, giving bond order 5/2=2.5.

Adding one more to give CN- would give the bond order 6/2 = 3. (If we added more electrons, each one would lower the bond order.)

Given a series of molecules with identical skeletal structures, the one with the highest bond order has the highest bond energy:

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Lewis structures will verify that CN- has a triple bond, but they do not work particularly well for CN+ and CN.

learn more about bond orders at

brainly.com/question/9713842

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