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alexandr402 [8]
3 years ago
5

15.Vicinal coupling is:A)coupling between 1H nuclei attached to adjacent C atoms.B)coupling between 1H nuclei in an alkene.C)cou

pling between 1H nuclei attached to the same C atom.D)coupling between 1H nuclei in an alkane.
Chemistry
1 answer:
timurjin [86]3 years ago
6 0

Answer:

A)coupling between 1H nuclei attached to adjacent C atoms.

Explanation:

The word ‘vicinal’ in chemistry means three bonds from the functional groups. The two functional groups are in a relationship with the atoms in adjacent position to them.

The 1H nuclei consists of two Hydrogen nucleus which acts as the functional groups. They are however attached and in a relationship with the adjacent C atoms. This makes option A the right choice.

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<h3>How do we calculate pH of weak base?</h3>

pH of the weak base will be calculate by using the Henderson Hasselbalch equation as:

pH = pKb + log([HB⁺]/[B])

pKb = -log(1.8×10⁻⁶) = 5.7

Chemical reaction for C₆H₅NH₂ is:

                          C₆H₅NH₂ + H₂O → C₆H₅NH₃⁺ + OH⁻

Initial:                     0.25                           0            0

Change:                    -x                             x             x

Equilibrium:        0.25-x                           x             x

Base dissociation constant will be calculated as:
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Kb = x² / 0.25 - x

x is very small as compared to 0.25, so we neglect x from that term and by putting value of Kb, then the equation becomes:

1.8×10⁻⁶ = x² / 0.25

x² = (1.8×10⁻⁶)(0.25)

x = 0.67×10⁻³ M = [C₆H₅NH₃⁺]

On putting all these values on the above equation of pH, we get

pH = 5.7 + log(0.67×10⁻³/0.25)

pH = 3.13

Hence pH of the solution is 3.13.

To know more about Henderson Hasselbalch equation, visit the below link:
brainly.com/question/13651361

#SPJ4

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