Answer:
0.44 moles
Explanation:
Given that :
A mixture of water and graphite is heated to 600 K in a 1 L container. When the system comes to equilibrium it contains 0.17 mol of H2, 0.17 mol of CO, 0.74 mol of H2O, and some graphite.
The equilibrium constant ![K_c= \dfrac{[CO][H_2]}{[H_2O]}](https://tex.z-dn.net/?f=K_c%3D%20%20%5Cdfrac%7B%5BCO%5D%5BH_2%5D%7D%7B%5BH_2O%5D%7D)
The equilibrium constant 
The equilibrium constant 
Some O2 is added to the system and a spark is applied so that the H2 reacts completely with the O2.
The equation for the reaction is :
Total mole of water now = 0.74+0.17
Total mole of water now = 0.91 moles
Again:
![0.03905 = \dfrac{[0.17+x][x]}{[0.91 -x]}](https://tex.z-dn.net/?f=0.03905%20%3D%20%20%5Cdfrac%7B%5B0.17%2Bx%5D%5Bx%5D%7D%7B%5B0.91%20-x%5D%7D)
0.03905(0.91 -x) = (0.17 +x)(x)
0.0355355 - 0.03905x = 0.17x + x²
0.0355355 +0.13095
x -x²
x² - 0.13095
x - 0.0355355 = 0
By using quadratic formula
x = 0.265 or x = -0.134
Going by the value with the positive integer; x = 0.265 moles
Total moles of CO in the flask when the system returns to equilibrium is :
= 0.17 + x
= 0.17 + 0.265
= 0.435 moles
=0.44 moles (to two significant figures)
Answer: The most likely partial pressures are 98.7MPa for NO₂ and 101.3MPa for N₂O₄
Explanation: To determine the partial pressures of each gas after the increase of pressure, it can be used the equilibrium constant Kp.
For the reaction 2NO₂ ⇄ N₂O₄, the equilibrium constant is:
Kp = 
where:
P(N₂O₄) and P(NO₂) are the partial pressure of each gas.
Calculating constant:
Kp = 
Kp = 0.0104
After the weights, the total pressure increase to 200 MPa. However, at equilibrium, the constant is the same.
P(N₂O₄) + P(NO₂) = 200
P(N₂O₄) = 200 - P(NO₂)
Kp =
0.0104 = ![\frac{200 - P(NO_{2}) }{[P(NO_{2} )]^{2}}](https://tex.z-dn.net/?f=%5Cfrac%7B200%20-%20P%28NO_%7B2%7D%29%20%20%7D%7B%5BP%28NO_%7B2%7D%20%29%5D%5E%7B2%7D%7D)
0.0104![[P(NO_{2} )]^{2}](https://tex.z-dn.net/?f=%5BP%28NO_%7B2%7D%20%29%5D%5E%7B2%7D)
+ 
- 200 = 0
Resolving the second degree equation:
= 
= 98.7
Find partial pressure of N₂O₄:
P(N₂O₄) = 200 - P(NO₂)
P(N₂O₄) = 200 - 98.7
P(N₂O₄) = 101.3
The partial pressures are = 98.7 MPa and P(N₂O₄) = 101.3 MPa
Atomic mass silicon = 28.085 u
1 mol Si ---------------- 28.085 g
? ------------------------ 245 g
245 x 1 / 28.085 => 8.72 mol
answer A
Yes it need to be like that cause when it like that it like that
