The freezing point depression is calculated through the equation,
ΔT = (kf) x m
where ΔT is the difference in temperature, kf is the freezing point depression constant (1.86°C/m), and m is the molality. Substituting the known values,
5.88 = (1.86)(m)
m is equal to 3.16m
Recall that molality is calculated through the equation,
molality = number of mols / kg of solvent
number of mols = (3.16)(1.25) = 3.95 moles
Then, we multiply the calculated amount in moles with the molar mass of ethylene glycol and the answer would be 244.9 g.
Answer is: the % ionization of hypochlorous acid is 0.14.
Balanced chemical
reaction (dissociation) of an aqueous solution of hypochlorous acid:
HClO(aq) ⇄ H⁺(aq) + ClO⁻(aq).
Ka = [H⁺] · [ClO⁻] / [HClO].
[H⁺] is equilibrium concentration of hydrogen cations or protons.
[ClO⁻] is equilibrium concentration of hypochlorite anions.
[HClO]
is equilibrium concentration of hypochlorous acid.
Ka is the acid
dissociation constant.
Ka(HClO) = 3.0·10⁻⁸.
c(HClO) = 0.015 M.
Ka(HClO) = α² · c(HClO).
α = √(3.0·10⁻⁸ ÷ 0.015).
α = 0.0014 · 100% = 0.14%.
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