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Tema [17]
3 years ago
8

Barium and lead both produce yellow precipitate with the chromate ion as part of their confirmation tests. if you had a sample t

hat possibly contained lead, barium, or both ions, outline a procedure for correctly identifying the cations present.
Chemistry
2 answers:
ehidna [41]3 years ago
8 0

Explanation:

Lead belongs to group 1 cations and barium belongs to the fifth group cations.

If the sample, contains lead then it can be precipitated by using dilute HCl as lead chloride. Barium, if present will not precipitate.

Confirmatory test for lead:

Dissolve the precipitate in hot water and centrifugate and divide the filtrate in 3 parts as lead chloride comes in the solution because it is soluble in hot water.

  • To the filtrate 1, add dilute sulfuric acid. The appearance of white precipitate confirms lead.
  • To the filtrate 2, add 2-3 mL of potassium chromate solution. The appearance of yellow precipitate confirms lead.
  • To the filtrate 3, add 2-3 mL of potassium iodide solution. The appearance of yellow precipitate confirms lead.

If barium is also present, it can be precipitated by using ammonium carbonate and can be confirmed by the addition of sulphurica cid which gives white precipitate and also addition of the potassium chromate solution. The appearance of yellow precipitate confirms barium. Also, barium imparts green color to the flame.

UkoKoshka [18]3 years ago
5 0
Barium is an element that is primarily used in fireworks because of its distinct green colour while on the other hand, lead is used in electrical industries due to its unique properties. The ions of these elements can simply be identified when its insoluble salts get precipitated by any process.
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<u>First of all, what is electrolysis?</u>

Electrolysis is the process of breaking down ionic substances using direct current.

<u>Important points about electrolysis </u>

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<h2><em><u>The answer to your question</u></em></h2>

1) The first step would be to clean the metal ring and sand it down because when the metal atoms from the electrolyte are deposited onto the ring, they will form a weak bond and they may simply 'fall' off. Also this could affect conductivity and the whole experiment. The more things you do accurately now, the more accurate your result will be.

2) You want to put the solution you are given in to the tank your going to be using.

3) This is basically the main part, you want to set up the circuit, I have attached a diagram at the bottom to show you the circuit. The copper rod will be the anode and the metal ring will be a cathode (ignore the elements).

4) Now turn on the circuit and you will start to see the solution spilt with the the solution now being split some going to the anode and some going the cathode.

5) Then a thin layer should form on the electrode.

Hope this helps :)

<h2><em><u></u></em></h2>

<em><u></u></em>

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