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Tema [17]
3 years ago
8

Barium and lead both produce yellow precipitate with the chromate ion as part of their confirmation tests. if you had a sample t

hat possibly contained lead, barium, or both ions, outline a procedure for correctly identifying the cations present.
Chemistry
2 answers:
ehidna [41]3 years ago
8 0

Explanation:

Lead belongs to group 1 cations and barium belongs to the fifth group cations.

If the sample, contains lead then it can be precipitated by using dilute HCl as lead chloride. Barium, if present will not precipitate.

Confirmatory test for lead:

Dissolve the precipitate in hot water and centrifugate and divide the filtrate in 3 parts as lead chloride comes in the solution because it is soluble in hot water.

  • To the filtrate 1, add dilute sulfuric acid. The appearance of white precipitate confirms lead.
  • To the filtrate 2, add 2-3 mL of potassium chromate solution. The appearance of yellow precipitate confirms lead.
  • To the filtrate 3, add 2-3 mL of potassium iodide solution. The appearance of yellow precipitate confirms lead.

If barium is also present, it can be precipitated by using ammonium carbonate and can be confirmed by the addition of sulphurica cid which gives white precipitate and also addition of the potassium chromate solution. The appearance of yellow precipitate confirms barium. Also, barium imparts green color to the flame.

UkoKoshka [18]3 years ago
5 0
Barium is an element that is primarily used in fireworks because of its distinct green colour while on the other hand, lead is used in electrical industries due to its unique properties. The ions of these elements can simply be identified when its insoluble salts get precipitated by any process.
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2 years ago
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Answer:

About 67 grams or 67.39 grams

Explanation:

First you would have to remember a few things:

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  a mole of water is 18.02 grams

  we also have to assume the ice is at 0 degrees C

Step 1

Now start with your ice.  The enthalpy of fusion for ice is calculated with this formula:

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Calculate how many moles of ice you have:

150g x (1 mol / 18.02 g) = 8.32 moles

Put that into the equation:

q = 8.32 mol x 6.02 = 50.09 kJ of energy to melt 150g of ice

Step 2

To raise 1 gram of water to the boiling point, it would take 4.18 joules times 100 (degrees C)  or 418 joules.

So if it takes 418 joules for just 1 gram of water, it would take 150 times that amount to raise 150g to 100 degrees C.  418 x 150 = 62,700 joules or 62.7 kilojoules.

So far you have already used 50.09 kJ to melt the ice and another 62.7 kJ to bring the water to boiling.  That's a total of 112.79 kJ.

Step 3

The final step is to see how much energy is left to vaporize the water.

Subtract the energy you used so far from what you were told you have.

265 kJ - 112.79 kJ = 152.21 kJ

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You know you only have 152.21 kJ left so find out how many moles that will vaporize.

152.21 kJ = mol x 40.68  or   mol = 152.21 / 40.68  = 3.74 moles

This tells you that you have vaporized 3.74 moles with the energy you have left.

Convert that back to grams.

3.74 mol   x  ( 18.02 g / 1 mol ) = 67.39 grams

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