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Julli [10]
2 years ago
13

A tank originally contains 100 gallons of fresh water. Then, water containing 0.5 lb of salt per gallon is poured into the tank

at a rate of 2 gallons per minute, and the mixture is allowed to leave at the same rate. After 10 minutes, the process is stopped and fresh water is poured in the tank at a rate of 9 gallons per minute, with the mixture again leaving at the same rate. Find the amount of salt in the tank at the end of an additional 10 minutes.
Chemistry
1 answer:
ValentinkaMS [17]2 years ago
7 0

Answer:

The amount of salt in the tank at the end of an additional 10 minutes are 4.38lb.

Explanation:

<u>Situation 1:</u>

Tank with 100 gallons of fresh water

<u>Situation 2:</u>

Tank with 100 gallons of fresh water + water with 0.5lb of salt per gallon

After 10 minutes, as the rate in which the new water is poured is 2 gallons per minute, the result is 20 gallons added (2×10=20) . And taking in account that the water contains 0.5 lb of salt per gallon the amount of salt added is 20×0.5= 10lb of salt.

That amount of salt is now in all the water inside the tank which is 100 gallons+ 20 gallons= 120 gallons. <em>That means that in situation 2 we have 10lb of salt in 120 gallons of water.</em>

That mixture is allowed to leave the tank at a rate of 2 gallons per minute so we will have after 10 minutes: 120 gallons- (2×10) gallons= 100 gallons remaining in the tank. And the amount of salt if we remember that we had 10lb in 120 gallons, now in 100 gallons we will have: (100 gallons × 10lb of salt)/  120 gallons= 8.33 lb of salt.

<u>Situation 3:</u>

Tank with 100 gallons of water with 8.33lb of salt.

After 10 minutes in which fresh water is poured in the tank at a rate of 9 gallons per minute, the result is: 9×10= 90 gallons added to the tank. So now we have 100+90=190 gallons of water in  the tank. <em>That means in situation 3 we have 8.33 lb of salt in 190 gallons of water. </em>

That mixture is leaving the tank at a rate of 9 gallons per minute so we have after 10 minutes: (190- (9×10))= 100 gallons of mixture remaining in the tank.

And the amount of salt if we remember that we had 8.33lb in 190 gallons, now in 100 gallons we will have: (100 gallons × 8.33lb of salt)/  190 gallons= 4.38 lb of salt.

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Calculate the pH of each of the following solutions: (a) 0.1000M Propanoic acid (HC3H5O2, Ka= 1.3x10-5 ) (b) 0.1000M sodium prop
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(a) The pH of 0.1000 M propanoic acid (HC3H5O2) is 2.9.

(b) The pH of 0.1000 M sodium propanoate (NaC3H5O2) is 8.9.

(c) The pH of 0.1000 M propanoic acid (HC3H5O2) and 0.1000 M sodium propanoate (NaC3H5O2) is 4.9.

<h3>Further explanation:</h3>

(a)

Given information:

The value of acid ionization constant for propanoic acid is  1.3 x 10^{-5} .

The initial concentration of propanoic acid is  .

To calculate:

The pH of 0.1000 M propanoic acid solution.

Solution:

Propanoic acid  is a weak acid. It ionizes partially in water as follows:

 

The expression for acid dissociation constant is,

                                                            …… (1)

Here,

 is ionization constant of propanoic acid.

is the equilibrium concentration of propanoate ion.

is the equilibrium concentration of hydronium ion.

 is the equilibrium concentration of propanoic acid.

ICE table (1):

 

Refer ICE table (1),

 

Substitute the values form the ICE table (1) in equation (1).

 

The approximation x is very small is valid. Therefore, the value of x can be neglected. Above equation can be modified as,

 

Rearrange above equation for x.

                                                                                                           …… (2)

Substitute   for   in equation (2) to calculate the value of x.

 

Therefore, from the ICE table (1) the concentration of hydronium ion is,

 .

The negative logarithm of hydronium ion concentration is defined as the pH of the solution. Mathematically,

                                                                                                               …… (3)

Substitute    for    in equation (3) to calculate the pH of the solution.

 

(b)

Given information:

The value of acid ionization constant for propanoic acid is  .

The initial concentration of sodium propanoate is  .

To calculate:

The pH of 0.1000 M sodium propanoate solution.

Solution:

Sodium propanoate  is conjugate base of weak propanoic acid. It undergoes hydrolysis in water to yield hydroxide ion in the solution as follows:

                                                        …… (4)

Propanoic acid  is a weak acid. It ionizes partially in water as follows:

                                                       …… (5)

Dissociation reaction for water is written as follows:

                                                                                       …… (6)

From equation (4), (5), and (6) the relationship between   and   is,

                                                                                                                              …… (7)

Substitute   for   and   for   in equation (7).

 

ICE table (2):

 

The expression for base dissociation constant is,

                                                                                                     …… (8)

Here,

is base ionization constant.

is the equilibrium concentration of propanoate ion.

is the equilibrium concentration of hydroxide ion.

 is the equilibrium concentration of propanoic acid.

From the ICE table (2),

 

Substitute the values form the ICE table (2) in equation (8).

 

The approximation y is very small is valid. Therefore, the value of y can be neglected. Above equation can be modified as,

 

Rearrange above equation for y.

                                                                                                           …… (9)

Substitute   for   in equation (9) to calculate the value of y.

 

Therefore, from the ICE table (2) the concentration of hydroxide ion is,

 

The negative logarithm of hydroxide ion concentration is defined as pOH of the solution. Mathematically,

                                                                                                           …… (10)

Substitute    for    in equation (10) to calculate pOH of the solution.

 

The relation between pH and pOH is as follows:

                                                                                                                   …… (11)

Substitute 5.057 for pOH in equation (11) to calculate the pH of the solution.

 

(c)

Given information:

The value of acid ionization constant for propanoic acid is  .

The initial concentration of sodium propanoate is  .

The initial concentration of sodium propanoate is  .

To calculate:

The pH of 0.1000 M sodium propanoate and 0.1000 M propanoic acid solution.

Solution:

Propanoic acid is a weak acid, and sodium propanoate is salt of the conjugate base of propanoic acid. Thus, propanoic acid and sodium propanoate will form a buffer system.

The pH of the buffer solution can be determined with the help of the Henderson-Hasselbalch equation. Mathematically,

 

For propanoic acid and sodium propanoate buffer system, the Henderson-Hasselbalch equation can be modified as,

                                                                                               …… (12)

The negative logarithm of acid ionization constant is equal to  .

                                                                                                                …… (13)

Substitute   for  in equation (13).

 

Substitute    for  ,   for   and 4.9 for    in equation (12).

 

Learn more:

1. About Henderson-Hasselbalch equation brainly.com/question/12999557

2. Learn more about how to calculate moles of the base in given volume brainly.com/question/4283309

Answer details:

Grade: Senior School

Subject: Chemistry

Chapter: Ionic equilibria

Keywords: ionic equilibrium, propanoic acid, sodium propanoate, ionization constant, weak acid, conjugate base, equilibrium concentration, hydronium ion, hydroxide ion, pH, pOH, ICE table, negative logarithm, buffer solution, Henderson-Hasselbalch equation, 0.1000 M, 4.9, 8.9, 2.9.

3 0
3 years ago
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