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Bingel [31]
3 years ago
14

A 32.5 g iron rod, initially at 22.4 ∘C, is submerged into an unknown mass of water at 63.0 ∘C, in an insulated container. The f

inal temperature of the mixture upon reaching thermal equilibrium is 59.7 ∘C. Part A What is the mass of the water? Express your answer to two significant figures and include the appropriate units.
Chemistry
1 answer:
Allisa [31]3 years ago
8 0

Answer:

The mass of water m_{w} = 39.18 gm

Explanation:

Mass of iron m_{iron} = 32.5 gm

Initial temperature of iron T_{1} = 22.4°c = 295.4 K

Specific heat of iron  C_{iron} = 0.448 \frac{KJ}{kg K}

Mass of water = m_{w}

Specific heat of water  C_{w} = 4.2 \frac{KJ}{kg  K}

Initial temperature of water T_{2} = 336 K  

Final temperature after equilibrium T_{f} = 59.7°c = 332.7 K

When iron rod is submerged into water then

Heat lost by water  = Heat gain by iron rod

m_{w} C_{w} (T_{2} - T_{f} ) =  m_{iron} C_{iron} ( T_{f} - T_{1} )

Put all the values in above formula we get

m_{w} × 4.2 × ( 336 - 332.7 ) = 32.5 × 0.448 × ( 332.7 - 295.4 )

m_{w} = 39.18 gm

Therefore the mass of water m_{w} = 39.18 gm

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3 years ago
A mixture of 1.374g of H2 and 70.31g of Br2 is heated in a 2.00 L vessel at 700 K. These substances react as follows: H2(g) + Br
gregori [183]

Answer:

a. 0.139 M → [H₂] ; 0.217 M → [Br₂] ; 0.01 M → [HBr]

b. Kc =  3.31x10⁻³

Explanation:

                  H2(g)   +   Br2(g)     ⇄  2HBr(g)

Initial        1.374 g       70.31 g             -

reacts            X                X                2x

eq.           (1.374 - x)     (70.31-x)         2x

<em>In equilibrium I see, the grams I initially had minus some mass which has reacted. In products I have the double of that mass, because the stoichiometry.</em>

So I have the mass in equilibrium, of H2 and of course I can know the mass which has reacted.

1.374g - x = 0.556 g

1.374g - 0.556 g = x = 0.808 g (This is the mass which has reacted)

70.31g  - 0.808 g = 69.502 g (Mass in equilibrium of Br2)

2 . 0.808 g = 1.616 g (Mass in equibrium of HBr)

By molar mass, we can kwow the moles.

Molar mass H2: 2 g/m  

Moles = mass / molar mass  → 0.556 g / 2 g/m = 0.278 moles

Molar mass Br2: 159.80 g/m

Moles = mass / molar mass  → 69.502 g / 159.80 g/m = 0.434 moles

Molar mass HBr: 80.9 g/m

Moles = mass / molar mass → 1.616 g / 80.9 g/m = 0.02 moles

The moles are not molarity. In equilibrium, to calculate Kc we need molarity (moles/L). The moles we have calculated are in 2 L of mixture so:

moles / L = molarity

0.278 moles / 2L = 0.139 M → [H₂]

0.434 moles / 2L = 0.217 M → [Br₂]

0.02 moles / 2L = 0.01 M → [HBr]

Kc =  [HBr]² / ([H₂] . [Br₂])

Kc = 0.01² / (0.139 . 0.217) = 3.31x10⁻³

6 0
3 years ago
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