Answer: pH = 2,897 , basic![[H+][OH-] = 10^{-14} ==> [H+] = \frac{10^{-14}}{7,89*10^{-12} } =\frac{1}{789} \\pH= -lg([H+]) = 2,897 \\pH basic](https://tex.z-dn.net/?f=%5BH%2B%5D%5BOH-%5D%20%3D%2010%5E%7B-14%7D%20%3D%3D%3E%20%5BH%2B%5D%20%3D%20%5Cfrac%7B10%5E%7B-14%7D%7D%7B7%2C89%2A10%5E%7B-12%7D%20%7D%20%3D%5Cfrac%7B1%7D%7B789%7D%20%5C%5CpH%3D%20-lg%28%5BH%2B%5D%29%20%3D%202%2C897%20%5C%5CpH%3C7%20%3D%3D%3E%20basic)
Explanation:
1) Chemical reaction: HCN + H₂O → CN⁻ + H₃O⁺.
c(HCN) = 2,2 M = 2,2 mol/L.
pKa(HCN) = 9,21.
Ka = 6,16·10⁻¹⁰.
[CN⁻] = [H₃O⁺] = x.
[HCN<span>] = 2,2 M - x.
</span>Ka = [CN⁻] · [H₃O⁺] / [HCN].
6,16·10⁻¹⁰ = x² / 2,2 M -x.
Solve quadratic equation: [CN⁻] = [H₃O⁺] = 0,0000346 M.
[HCN] = 2,2 M - 0,0000346 M = 2,199 M.
2) pH = - log[H₃O⁺].
pH = -log( 0,0000346 M).
pH = 4,46.
Hydrocyanic acid and hydronium ion (H₃O⁺) are acids. Cyanide anion (CN⁻) is the strongest base in the system, cyanide anion accept protons in chemical reaction.
pKb = pKw - pKa.
pKb = 14 - 9,21 = 4,79.
Nuclear explosion i hope that correct
T = 2T , P = 2P as given in the question
Volume = mass *density
Now apply ideal gas law
PV=nRT
V = nRT/P
substitute value of V and P
V = nR2T/2P
V =nRT/P
mass*density = nRT/P
density will not change
