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valina [46]
3 years ago
8

A solution is prepared by dissolving 0.56 g of benzoic acid (C6H5CO2H, Ka ???? 6.4 ???? 10????5) in enough water to make 1.0 L o

f solution. Calculate [C6H5CO2H], [C6H5CO2????], [H????], [OH????], and the pH of this solution.
Chemistry
1 answer:
garri49 [273]3 years ago
7 0

Answer:

[H⁺] = 6.083x10⁻⁴ M, [C₆H₅OO⁻] = 6.083x10⁻⁴ M, [C₆H₅OOH] = 3.98x10⁻³M, pH = 3.22

Explanation:

Data: we have 0.56 gr of benzoic acid, disolved in 1Lt of water. Kₐ = 6.4x10⁻⁵

M (molar mass) of BA (Benzoic Acid) = 122 g/mol

Then, the inicial concentration is 0.56/122 = 4.59x10⁻³ M

We should consider the equation once it reaches the equilibrium:

C₆H₅COOH ⇄ C₆H₅COO⁻ + H⁺

  C - x                      x              x

And, for the Kₐ:

Kₐ = [H⁺][C₆H₅COO⁻]/[C₆H₅COOH] = x²/(C-x) , where C = 4.59x10⁻³

Then: x² + Kₐx - KₐC = 0

x² + 6.4x10⁻⁵ - 2.9x10⁻⁷ = 0

Resolving this cuadratic equation (remember to use Baskara equation), we obtain:

x = 6.083x10⁻⁴ M

Then: [H⁺] = [C₆H₅COO⁻] = 6.083x10⁻⁴ M

[C₆H₅COOH] = C - x = 3.98x10⁻³ M

pH = -Log [H⁺] = 3.22

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1. Take the reaction: NH3 + O2 + NO + H2O. In an experiment, 3.25g of NH3 are allowed
Rudiy27

Answer:

5.74g of NO

Explanation:

Step 1:

The balanced equation for the reaction. This is given below:

4NH3 + 5O2 —> 4NO + 6H2O

Step 2:

Determination of the masses of NH3 and O2 that reacted and the mass of NO produced from the balanced equation. This is illustrated below:

Molar Mass of NH3 = 14 + (3x1) = 14 + 3 = 17g/mol

Mass of NH3 from the balanced equation = 4 x 17 = 68g

Molar Mass of O2 = 16x2 = 32g/mol

Mass of O2 from the balanced equation = 5 x 32 = 160g

Molar Mass of NO = 14 + 16 = 30g/mol

Mass of NO from the balanced equation = 4 x 30 = 120g

From the balanced equation above,

68g of NH3 reacted with 160g of O2 to produce 120g of NO.

Step 3:

Determination of the limiting reactant.

We need to determine the limiting because it will be used to calculate the maximum yield of the reaction. This is illustrated below:

From the balanced equation above,

68g of NH3 reacted with 160g of O2.

Therefore, 3.25g of NH3 will react with = (3.25 x 160)/68 = 7.65g of O2.

From the simple illustration above, we can see that lesser mass of O2 is needed to react with 3.25g of NH3. Therefore, NH3 is the limiting reactant while O2 is the excess reactant.

Step 4:

Determination of the mass of NO produced from the reaction.

In this case the limiting reactant will be used because all of it were used in the reaction.

The limiting reactant is NH3.

From the balanced equation above,

68g of NH3 reacted to produce 120g of NO.

Therefore, 3.25g of NH3 will react to produce = (3.25 x 120)/68 = 5.74g of NO.

From the calculations made above, 5.74g of NO is produced.

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