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For methyl chloride at 100°C the second and third virial coefficients are: B = −242.5 cm 3 ·mol −1 C = 25,200 cm 6 ·mol −2 Calcu

bogdanovich [222]

Answer:

a)W=12.62 kJ/mol

b)W=12.59 kJ/mol

Explanation:

At T = 100 °C the second and third virial coefficients are

B = -242.5 cm^3 mol^-1

C = 25200 cm^6 mo1^-2

Now according isothermal work of one mole methyl gas is

W=- $\int\limits^a_b {P} \, dV$

a= $v_2\\$

b= $v_1$

from virial equation

$\frac{PV}{RT}=z=1+\frac{B}{V}+\frac{C}{V^2}\\ \\P=RT(1+\frac{B}{V} +\frac{C}{V^2})\frac{1}{V}\\$

And

$W=-\int\limits^a_b {RT(1+\frac{B}{V} +\frac{C}{V^2}\frac{1}{V} } \, dV$

a= $v_2\\$

b= $v_1$

Now calculate V1 and V2 at given condition

$\frac{P1V1}{RT} = 1+\frac{B}{v_1} +\frac{C}{v_1^2}$

Substitute given values $P_1\\$ = 1 x 10^5 , T = 373.15 and given values of coefficients we get

$10^5(v_1)/8.314*373.15=1-242.5/v_1+25200/v_1^2$

Solve for V1 by iterative or alternative cubic equation solver we get

$v_1=30780 cm^3/mol$

Similarly solve for state 2 at P2 = 50 bar we get

$v_1=241.33 cm^3/mol$

Now

$W=-\int\limits^a_b {RT(1+\frac{B}{V} +\frac{C}{V^2}\frac{1}{V} } \, dV$

a=241.33

b=30780

After performing integration we get work done on the system is

W=12.62 kJ/mol

(b) for Z = 1 + B' P +C' P^2 = PV/RT by performing differential we get

dV=RT(-1/p^2+0+C')dP

Hence work done on the system is

$W=-\int\limits^a_b {P(RT(-1/p^2+0+C')} \, dP$

a= $v_2\\$

b= $v_1$

by substituting given limit and P = 1 bar , P2 = 50 bar and T = 373 K we get work

W=12.59 kJ/mol

The work by differ between a and b because the conversion of constant of virial coefficients are valid only for infinite series

8 0

3 years ago

Where loads are likely to be on continuously, the calculated load for branch circuits and feeders must be figured at (100%) (125

Anna [14]

Where loads are likely to be on continuously, the calculated load for branch circuits and feeders must be figured at 125%.

Section 210.19(A)(1) permits the bigger of the two values listed below to be utilized as the connectors 's ultimate size for sizing an ungrounded branch circuit conductor:

Without any extra adjustments or corrections, either 125% of the continuous load, OR

When adjustment and corrective factors are applied, the load is 100% (not 125% as stated previously).

This will be the same in the 2020 NEC. The introduction of new exception 2 is what has changed. To comprehend this new exception, one must study it very carefully. A part of a branch circuit connected to pressure connectors (such as power distribution blocks) that complies with 110.14(C)(2) may now be sized using the continuous load plus the noncontiguous load instead of 125% of the continuous load thanks to the new exception.

To know more about connectors click here:

brainly.com/question/16987039

#SPJ4

4 0

11 months ago

Engineers are designing a cylindrical air tank and are trying to determine the dimensions of the tank. The proposed material for

lana66690 [7]

Answer:

The length of tank is found to be 0.6 m or 600 mm

Explanation:

In order to determine the length, we need to find a volume for the tank.

For this purpose, we use ideal gas equation:

PV = nRT

n = no. of moles = m/M

Therefore,

PV = (m/M)(RT)

V = (mRT)/(MP)

where,

V = volume of air = volume of container

m = mass of air = 4.64 kg

R = General Gas Constant = 8.314 J/mol.k

T = temperature of air = 10°C + 273 = 283 K

M = molecular mass of air = 0.02897 kg/mol

P = Pressure of Air = 20 MPa = 20 x 10^6 N/m²

V = (4.64 kg)(8.314 J/mol.k)(283 k)/(0.02897 kg/mol)(20 x 10^6 N/m²)

V = 0.01884 m³

Now, the volume of cylindrical tank is given as:

V = 0.01884 m³ = π(Diameter/2)²(Length)

Length = (0.01884 m³)(4)/π(0.2 m)²

<u>Length = 0.6 m = 600 mm</u>

4 0

3 years ago

Match each context to the type of the law that is most suitable for it.

Bas_tet [7]

Answer:

sorry i dont understand the answer

Explanation:

but i think its a xd jk psml lol

5 0

3 years ago

A 5-cm-diameter shaft rotates at 4500 rpm in a 15-cmlong, 8-cm-outer-diameter cast iron bearing (k = 70 W/m·K) with a uniform cl

-BARSIC- [3]

Answer:

(a) the rate of heat transfer to the coolant is Q = 139.71W

(b) the surface temperature of the shaft T = 40.97°C

(c) the mechanical power wasted by the viscous dissipation in oil 22.2kW

Explanation:

See explanation in the attached files

5 0

3 years ago