original equation : As - 1 As -1 Na - 1 Na - 3 O - 1 O- 3 H - 1 H -2 As we can see they are obviously not balanced. so we have to manipulate it so it can equal.
new balanced equation:
2As + 6NaOH ------>>> 2Na3AsO3 + 3H2
As - 1(2) = 2 As - 1(2) = 2 Na - 1(6) = 6 Na - 3(2) = 6 O -1(6) = 6 O - 3(2) = 6 H - 1(6) = 6 H - 2(3) = 6 As we can see, both sides are balanced