Question

What typically occurs in a substance where hydrogen bonding exists when compared to the same substance without H-bonds?

Answer 1

Answer:

B) Increase in boiling point and decrease in vapor pressure

Explanation:

Vapor pressure is inversely related  to the Boiling point , as

higher the boiling point, lower the vapor pressure. and

Lower the boiling point, higher the vapor pressure.

Hydrogen bonding.

The electrostatic attraction between Hydrogen , bonded to electronegative atom like F, O, N and the more electronegative atom is called as Hydrogen bonding.

For example -

In alcohols, - OH group has Hydrogen that is bonded to more electronegative atom O.

As ,  

Extra energy is required to break Hydrogen bonds.

because the substance which exhibits Hydrogen bonding have lower vapor pressure than that of the substance with out Hydrogen bonding.

Hence , the substance with Hydrogen bonding , has higher boiling point,.

Hence , the correct option is  Increase in boiling point and decrease in vapor pressure .