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Sergio [31]
4 years ago
11

Liquid dimethyl disulfide (CH3SSCH3) flows through a pipe with a mass flow rate of 86.0 g's. Given that the density of dimethyl

disulfide is 1.0625 g/cm, find: The molar flow rate in molimin: Number mol/min The volumetric flow rate in L/hr.
Chemistry
1 answer:
AURORKA [14]4 years ago
3 0

Explanation:

Molar mass of CH_{3}SSCH_{3} is 94 g/mol. As it is known that number of moles is equal to mass of a substance divided by its molar mass.

Then, calculate the number of moles as follows.

     No. of moles = \frac{86.0 g}{94 g/mol} in 1 s

                           = 0.914 mol

So, in 60 sec number of moles will be equal to 0.914 x 60 = 54.89 mol/min.

Hence, the molar flow rate = 54.89 mol/min

Also, density is equal to mass of a substance divided by its volume.

                    Density = \frac{mass}{volume}

                      Volume = \frac{mass}{Density}

                                     = \frac{86.0 g}{1.0625 g/cm^{3}}

                                     = 80.941 cm^{3}

As, 80.941 cm^{3} of volume flows in 1 s . Therefore, flow of volume in 1 hour will be calculated as follows.

                 In 1 hr = 80.941 cm^{3} \times 3600

                            = 291388.24 cm^{3}/hr

Since, 1 cm^{3} = 0.001 L.

So,              291388.24 cm^{3}/hr \times 0.001 L/cm^{3}

                            = 291.38824 L/hr

Thus, we can conclude that molar flow rate in mol/min is 54.89 mol/min and the volumetric flow rate in L/hr is 291.38824 L/hr.

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In pure water at 25 °C, the concentration of a saturated solution of CuF2 is 7.4 × 10−3 M. If measured at the same temperature,
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The concentration of a saturated solution of CuF₂ in aqueous 0.20 M NaF is  4.0×10⁻⁵ M.

Explanation:

Consider the ICE take for the solubility of the solid, CuF₂ as:

                                  CuF₂    ⇄     Cu²⁺ +    2F⁻

At t=0                            x                 -              -

At t =equilibrium      (x-s)                s           2s          

The expression for Solubility product for CuF₂ is:

K_{sp}=\left [ Cu^{2+} \right ]\left [ F^- \right ]^2

K_{sp}=s\times {2s}^2

K_{sp}=4s^3

Given  s = 7.4×10⁻³ M

So, Ksp is:

K_{sp}=4\times (7.4\times 10^{-3})^3

K_{sp}=4\times (7.4\times 10^{-3})^3

Ksp = 1.6209×10⁻⁶

Now, we have to calculate the solubility of CuF₂ in NaF.

Thus, NaF already contain 0.20 M F⁻ ions

Consider the ICE take for the solubility of the solid, CuF₂ in NaFas:

                                  CuF₂    ⇄     Cu²⁺ +    2F⁻

At t=0                            x                 -            0.20

At t =equilibrium      (x-s')             s'         0.20+2s'         

The expression for Solubility product for CuF₂ is:

K_{sp}=\left [ Cu^{2+} \right ]\left [ F^- \right ]^2

1.6209\times 10^{-6}={s}'\times ({0.20+2{s}'})^2

Solving for s', we get

<u>s' = 4.0×10⁻⁵ M</u>

<u>The concentration of a saturated solution of CuF₂ in aqueous 0.20 M NaF is  4.0×10⁻⁵ M.</u>

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