1) Calculate the molarity of a solution produced by dissolving 35.7 g of solid Cu(ClO3)2 in enough water to make 250 mL of solut
1 answer:
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Answer :
The rate law expression for zero order reaction will be:
The rate law expression for first order reaction will be:
The rate law expression for second order reaction will be:
Zero order reaction : There is no affect on the rate law.
First order reaction : The rate law becomes doubled.
Second order reaction : The rate law becomes quadrupled.
Explanation :
Rate law : It is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.
The given reaction is:
The rate law expression for zero order reaction will be:
The rate law expression for first order reaction will be:
The rate law expression for second order reaction will be:
Now we have to determine that if doubling of the concentration of A then the rate of reaction will be:
As we know that the zero order reaction does not depend on the concentration of reactant. So, there is no affect on the rate law.
As we know that the first order reaction depend on the concentration of reactant. So, the rate law becomes doubled.
As we know that the second order reaction depend on the concentration of reactant. So, the rate law becomes quadrupled.
Answer:
Part a: The IR spectrum is not sufficient due to the similar radical group presence in both product and reactants.
Part b: Mass Spectrum data is required in addition to the IR data for confirming the presence of recrystallized product.
Part c: The additional data is consistent with the expectations as the data is in support of that.
Explanation:
Part a
Acetanilide has a characteristic IR peak at around 3100-3200 cm^-1 (N-H Stretching) and 1500-1680 cm^-1 (C=O Stretching). Since a similar radical group () is present in the 4-bromoacetanilide, thus it is difficult to affirm the presence of the product solely on the basis of IR spectrum.
Part b
Mass Spectral data will affirm the presence of recrystallized product with certainty.
Part c
4-bromoacetanilide will have peak at two points (213 & 215) corresponding to the two Bromine isotopes (79 & 81).
Also parent peak at 171 (=43) will be in 49:51 due to presence of Bromine atoms.