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Gnesinka [82]
3 years ago
12

Sulfur reacts with oxygen to form sulfur dioxide (SO2(g), Hf = –296.8 kJ/mol) according to the equation below.

Chemistry
2 answers:
Pavel [41]3 years ago
7 0
Given that the reactants are the very consituents (elements)  of the final compound, the enthalpy change of this reaction is the same  heat of formation, Hf.

That means that the enthalpy chage for the reaction is -296.8 kj/mol
Liono4ka [1.6K]3 years ago
6 0

Answer : The enthalpy change for the reaction is -296.8 kJ/mol

Explanation :

Enthalpy change : It is defined as the difference in enthalpies of all the product and the reactants each multiplied with their respective number of moles. It is represented as \Delta H^o

The equation used to calculate enthalpy change is of a reaction is:  

\Delta H^o_{rxn}=\sum [n\times \Delta H^o_f(product)]-\sum [n\times \Delta H^o_f(reactant)]

The equilibrium reaction follows:

S(s)+O_2(g)\rightleftharpoons SO_2(g)

The equation for the enthalpy change of the above reaction is:

\Delta H^o_{rxn}=(1\times \Delta H^o_f_{(SO_2(g))})-(1\times \Delta H^o_f_{(S(s))}+1\times \Delta H^o_f_{(O_2(g))})

We are given:

\Delta H^o_f_{(SO_2(g))}=-296.8kJ/mol\\\Delta H^o_f_{(O_2(g))}=0kJ/mol\\\Delta H^o_f_{(S(s))}=0kJ/mol

Putting values in above equation, we get:

\Delta H^o_{rxn}=(1\times -296.8)-(1\times 0+1\times 0)=-296.8kJ/mol

Therefore, the enthalpy change for the reaction is -296.8 kJ/mol

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Ni2+(aq) + 6 NH3(aq) ⇌ Ni(NH3)6 2+(aq)
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Answer:

a) ΔGº= -49,9 KJ/mol = - 50 KJ/mol

b) The reaction  goes to the right to formation of products

c) ΔG= 84,42 KJ/mol. The direction is to reactive, to the left

Explanation:

a) ΔGº= - RTLnKf

You need to convert Cº to K. 25ºC=298K

Then, ΔGº= - 3,814 J/molK * 298K* Ln(5.6 *10^8)= - 49906 J/mol = -49,9 KJ/mol = - 50 KJ/mol

b) The ΔGº < 0, that means the direct reaction is spontaneous when te reactive and products are in standard state. In other words the reaction goes to the right, to formation of products

c) The general ecuation for chemical reaction is aA + bB → cD + dD. Thus

ΔG=ΔGº + RTLn (([C]^c*[D]^d)/[A]^a*[B]^b)

In this case,

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ΔG >0 means the reaction isn't spontaneous in the direction of the products. Therefore the direction is to reactive, to the left

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