Convert the following to Kelvin 12) 0° C 13) -50° C 14) 90° C 15) -20° C
2 answers:
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Answer:
See explanation and images attached
Explanation:
a) In the mechanism for the acid catalysed esterification of propanoic acid using ethanol, we can see that the first step is the protonation of the acid followed by nucleophillic attack of the alcohol. Loss of water and consequent deprotonation regenerates the acid catalyst. We can see the fate of the 18O labelled ethanol in the mechanism shown.
b) In the second mechanism, an unnamed ester is hydrolysed using an acid catalyst. The attack of the acid and subsequent nucleophillic attack of water labelled with 18O leads to the incorporation of this 18O into the product acid as shown in the mechanism attached to this answer.
Answer: 4-allylanisole
Explanation: The doublets behind the 7 ppm belongs to the
para-substituted benzene ring. The three single-proton multi-plets around 5−6 ppm predicts that there has to be a single subsituted alkene group
A single plus a doublet around 3-4 ppm belongs to CH3 and CH2 Groups as they could be attached to the subsituted alkene group.
Moreover the interpretation of the NMR that there is no peak with a higher intensity for >180 ppm represents an absence of Carbonyl group.
The Predicted Number is attached from a chemical database along with their peaks information
