The emf is equal to the work done on the charge per unit charge (ϵ=dWdq) when there is no current flowing. Since the unit for work is the joule and the unit for charge is the coulomb, the unit for emf is the volt (1V=1J/C).
The EMF or electromotive force is the energy supplied by a battery or a cell per coulomb (Q) of charge passing through it. The magnitude of emf is equal to V (potential difference) across the cell terminals when there is no current flowing through the circuit. (byjus)
