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jasenka [17]
3 years ago
11

Now, Johnny the pool guy must add enough Na2CO3 to get the pH back up to 7.60. How many grams of Na2CO3 does Johnny need to add

to the pool to do this? You can assume this is the neutralization reaction. Na2CO3 + H+ → 2 Na+ + HCO−
Chemistry
1 answer:
vaieri [72.5K]3 years ago
5 0

Answer:

m = 3.4126 g

Explanation:

First, the question is incomplete but I already put in the comments the rest of the question.

Let's solve the first two questions, and then the actual question you are asking here to give you a better explanation of how to do it.

1) We need the volume of the pool, in this case is easy. Assuming the pool is rectangular, we use the volume of a parallelepiped which is the following:

V = h * d * w

We have the data, but first we will convert the feet to centimeter. This is because is easier to work the volume in cm³ than in feet.

So the height, width and depth of the pool in centimeter are:

h = 32 * 30.48 = 975.36 cm

w = 18 * 30.48 = 548.64 cm

d = 5.3 * 30.48 = 161.54 cm

Now the volume:

V = 975.36 * 548.64 * 161.54

V = 86,443,528.79 cm³ or 86,443,528.79 mL or 86,443.5 L

2) If the pool has a pH of 6.4, the concentration of H+ can be calculated with the following expression:

[H+] = antlog(-pH) or 10^(-pH)

Replacing we have:

[H+] = 10^(-6.4)

[H+] = 3.98x10^-7 M

3) Finally the question you are asking for.

According to the reaction:

Na2CO3 + H+ → 2Na+ + HCO3−

We can see that there is ratio of 1:1 between the H+ and the Na2CO3, so, if we have initially a concentration of 3.98x10^-7 M, the difference between the new concentration of H+ and the innitial, will give the concentration to be added to the pool to raise the pH. Then, with the molecular weight of Na2CO3 (105.98 g/mol) we can know the mass needed.

The new concentration of [H+] is:

[H+] = 10^(-7.6) = 2.58x10^-8 M

The difference of both [H+] will give concentration of Na2CO3 used:

3.98x10^-7 - 2.58x10^-8 = 3.73x10^-7 M

The moles:

moles = 3.73x10^-7 * 86,443.5 = 0.0322 moles

Finally the mass:

m = 0.0322 * 105.98

m = 3.4126 g    

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The following data were collected for the rate of disappearance of NO in the reaction 2NO(g)+O2(g)→2NO2(g)::
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Answer:

a) The rate law is: v = k[NO]² [O₂]

b) The units are: M⁻² s⁻¹

c) The average value of the constant is: 7.11 x 10³ M⁻² s⁻¹

d) The rate of disappearance of NO is 0.8 M/s

e) The rate of disappearance of O₂ is 0.4 M/s

Explanation:

The experimental rates obtained can be expressed as follows:

v1 = k ([NO]₁)ᵃ ([O₂]₁)ᵇ = 1.41 x 10⁻² M/s

v2 = k ([NO]₂)ᵃ ([O₂]₂)ᵇ = 5.64 x 10⁻² M/s

v3 = k ([NO]₃)ᵃ ([O₂]₃)ᵇ = 1.13 x 10⁻¹ M/s

where:

k = rate constant

[NO]₁ = concentration of NO in experiment 1

[NO]₂ = concentration of NO in experiment 2

[NO]₃ = concentration of NO in experiment 3

[O₂]₁ = concentration of O₂ in experiment 1

[O₂]₂ = concentration of O₂ in experiment 2

[O₂]₃ = concentration of O₂ in experiment 3

a and b = order of the reaction for each reactive respectively.

We can see these equivalences:

[NO]₂ = 2[NO]₁

[O₂]₂ = [O₂]₁

[NO]₃ = [NO]₂

[O₂]₃ = 2[O₂]₂

So, v2 can be written in terms of the concentrations used in experiment 1 replacing [NO]₂ for 2[NO]₁ and [O₂]₂ by [O₂]₁ :

v2 = k (2 [NO]₁)ᵃ ([O₂]₁)ᵇ

If we rationalize v2/v1, we will have:

v2/v1 = k *2ᵃ * ([NO]₁)ᵃ * ([O₂]₁)ᵇ / k * ([NO]₁)ᵃ * ([O₂]₁)ᵇ (the exponent "a" has been distributed)

v2/v1 = 2ᵃ

ln(v2/v1) = a ln2

ln(v2/v1) / ln 2 = a

a = 2

(Please review the logarithmic properties if neccesary)

In the same way, we can find b using the data from experiment 2 and 3 and writting v3 in terms of the concentrations used in experiment 2:

v3/v2 = k ([NO]₂)² * 2ᵇ * ([O₂]₁)ᵇ / k * ([NO]₂)² * ([O₂]₂)ᵇ

v3/v2 = 2ᵇ

ln(v3/v2) = b ln 2

ln(v3/v2) / ln 2 = b

b = 1

Then, the rate law for the reaction is:

<u>v = k[NO]² [O₂]</u>

Since the unit of v is M/s and the product of the concentrations will give a unit of M³, the units of k are:

M/s = k * M³

M/s * M⁻³ = k

<u>M⁻² s⁻¹ = k </u>

To obtain the value of k, we can solve this equation for every experiment:

k = v / [NO]² [O₂]

for experiment 1:

k = 1.41 x 10⁻² M/s / (0.0126 M)² * 0.0125 M = 7.11 x 10³ M⁻² s⁻¹

for experiment 2:

k = 7.11 x 10³ M⁻² s⁻¹

for experiment 3:

k = 7.12 x 10³ M⁻² s⁻¹

The average value of k is then:

(7.11 + 7.11 + 7.12) x 10³ M⁻² s⁻¹ / 3 = <u>7.11 x 10³ M⁻² s⁻¹ </u>

The rate of the reaction when [NO] = 0.0750 M and [O2] =0.0100 M is:

v = k [NO]² [O₂]

The rate of the reaction in terms of the disappearance of NO can be written this way:

v = 1/2(Δ [NO] / Δt) (it is divided by 2 because of the stoichiometric coefficient of NO)

where (Δ [NO] / Δt) is the rate of disappearance of NO.

Then, calculating v with the data provided by the problem:

v = 7.11 x 10³ M⁻² s⁻¹ * (0.0750M)² * 0.0100M = 0.4 M/s

Then, the rate of disappearance of NO will be:

2v = Δ [NO] / Δt = <u>0.8 M/s</u>

The rate of disappearance of O₂ has to be half the rate of disappearance of NO because two moles of NO react with one of O₂. Then Δ [O₂] / Δt = <u>0.4 M/s</u>

With calculations:

v = Δ [O₂] / Δt = 0.4 M/s (since the stoichiometric coefficient is 1, the rate of disappearance of O₂ equals the rate of the reaction).

3 0
3 years ago
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