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crimeas [40]
3 years ago
10

A student prepares a weak acid solution by dissolving 0.2000 g HZ to give 100. mL solution. The titration requires 33.5 mL of 0.

1025 M NaOH. Calculate the molar mass of the acid. WebAssign will check your answer for the correct number of significant figures. g/mol (a) Would the molar mass be too high, too low, or unaffected if the student accidentally used 0.1000 g in the calculation
Chemistry
1 answer:
nexus9112 [7]3 years ago
3 0

Answer:

a)M=0.20/(0.335*0.1025)= 0.20/ 0.034 = 5.88 g/mol

b) if 0.100g is used instead of 0.200g

M = 0.1 / 0.034 = 2.94  hence the molar mass will be too low

Explanation:

0.2000 gHZ gives  100ml acid solution

33.5 ml of 0.1025 M NaOH  is required to prepare it

the moles = mass / molar mass

mass = 0.200 gHZ

moles = 0.0335*100 * 0.1025 = 0.034

therefore molar mass = mass / moles

                                  M=0.20/(0.335*0.1025)= 0.20/ 0.034 = 5.88

if 0.100g is used instead of 0.200g

M = 0.1 / 0.034 = 2.94  hence the molar mass will be too low

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Answer:

1) 1.52 atm.

2) 647.85 K.

3) 20.56 L.

4) 1.513 mole.

5) 254.22 K = -18.77 °C.

Explanation:

  • In all this points, we should use the law of ideal gas to solve this problem: PV = nRT.
  • Where, P is the pressure (atm), V is the volume (L), n is the number of moles, R is the general gas constant (0.082 L.atm/mol.K), and T is the temperature (K).

1) In this point; n, R, and T are constants and the variables are P and V.

P and V are inversely proportional to each other that if we have two cases we get: P1V1 = P2V2.

<u><em>In our problem:</em></u>

P1 = ??? <em>(is needed to be calculated) </em>and V1 = 45.0 L.

P2 = 5.7 atm and V2 = 12.0 L.

Then, the original pressure (P1) = P2V2 / V1 = (5.7 atm x 12.0 L) / (45.0 L) = 1.52 atm.


2) In this case, n and R are the constants and the variables are P, V, and T.

P and V are inversely proportional to each other and both of them are directly proportional to the temperature of the gas that if we have two cases we get: P1V1T2 = P2V2T1.

<u><em>In our problem:</em></u>

P1 = 212.0 kPa, V1 = 32.0 L, and T1 = 20.0 °C = (20 °C + 273) = 293 K.

P2 = 300.0 kPa, V2= 50.0 L, and T2 = ??? <em>(is needed to be calculated) </em>

Then, the temperature in the second case (T2) = P2V2T1 / P1V1 = (300.0 kPa x 50.0 L x 293 K) / (212.0 kPa x 32.0 L) = 647.85 K.


3) In this case, P, n and R are the constants and the variables are V, and T.

V and T are directly proportional to each other that if we have two cases we get: V1T2 = V2T1.

<u><em>In our problem:</em></u>

V1 = 25.0 L and T1 = 65.0 °C + 273 = 338 K.

V2 = ??? <em>(is needed to be calculated) </em> and T2 = 5.0 °C + 273 = 278 K.

Herein, there is no necessary to convert T into K.

Then, the volume in the second case (V2) = V1T2 / T1 = (25.0 L x 278 °C) / (338 °C) = 20.56 L.


4) We can get the number of moles that will fill the container from: n = PV/RT.

P = 250.0 kPa, we must convert the unit from kPa to atm; <em><u>101.325 kPa = 1.0 atm</u></em>, then P = (1.0 atm x 250.0 kPa) / (101.325 kPa) = 2.467 atm.

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R = 0.082 L.atm/mol.K.

T = 45 °C + 273 = 318 K.

Now, n = PV/RT = (2.467 atm x 16.0 L) / (0.082 L.atm/mol.K x 318 K) = 1.513 mole.


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P and T are directly proportional to each other that if we have two cases we get: P1T2 = P2T1.

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P1 = 2200.0 mmHg and T1 = ??? <em>(is needed to be calculated) </em>.

P2 = 2700.0 mmHg and T2 = 39.0 °C + 273 = 312.0 K.

Herein, there is no necessary to convert P into atm.

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