A Solution is a mixture of two or more substances_____

Chemistry

1 answer:

Ipatiy [6.2K]4 years ago

4 0

Answer:

In the same phase

Explanation:

Because when you make a solution you have to keep them in the same phase or you will oof.

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Consider the mechanism. Step 1: A+B↽−−⇀CA+B↽−−⇀C equilibrium Step 2: C+A⟶DC+A⟶D slow Overall: 2A+B⟶D2A+B⟶D Determine the rate la

tatuchka [14]

Answer:

rate = k[A][B] where k = k₂K

Explanation:

Your mechanism is a slow step with a prior equilibrium:

$\begin{array}{rrcl}\text{Step 1}:& \text{A + B} & \xrightarrow [k_{-1}]{k_{1}} & \text{C}\\\text{Step 2}: & \text{C + A} & \xrightarrow [ ]{k_{2}} & \text{D}\\\text{Overall}: & \text{2A + B} & \longrightarrow \, & \text{D}\\\end{array}$

(The arrow in Step 1 should be equilibrium arrows).

1. Write the rate equations:

$-\dfrac{\text{d[A]}}{\text{d}t} = -\dfrac{\text{d[B]}}{\text{d}t} = -k_{1}[\text{A}][\text{B}] + k_{1}[\text{C}]\\\\\dfrac{\text{d[C]}}{\text{d}t} = k_{1}[\text{A}][\text{B}] - k_{2}[\text{C}]\\\\\dfrac{\text{d[D]}}{\text{d}t} = k_{2}[\text{C}]$

2. Derive the rate law

Assume k₋₁ ≫ k₂.

Then, in effect, we have an equilibrium that is only slightly disturbed by C slowly reacting to form D.

In an equilibrium, the forward and reverse rates are equal:

k₁[A][B] = k₋₁[C]

[C] = (k₁/k₋₁)[A][B] = K[A][B] (K is the equilibrium constant)

rate = d[D]/dt = k₂[C] = k₂K[A][B] = k[A][B]

The rate law is

rate = k[A][B] where k = k₂K

5 0

4 years ago

What are the formal charges on the sulfur (s), carbon (c), and nitrogen (n) atoms, respectively, in the resonance structure that

sergiy2304 [10]

Answer:

Sulfur: -1

Carbon: 0

Nitrogen: 0

Explanation:

The thiocyanate ion SCN- can have only two resonance structures, which are:

S - C ≡ N <--------> S = C = N

In the first structure, we have one single bond and one triple bond, in this case, the negative charge is located in the sulfur. This is because Sulfur have 6 electrons and those electrons are present in the atom, (see picture below), and counting the electron that is sharing with the Carbon, the total electrons that sulfur has is 7 (It has one more than usual). Carbon and nitrogen are already stable with 0 of formal charge, because carbon can only have 4 electrons which 1 is sharing with sulfur and the other 3 with the nitrogen, and nitrogen have 5 electrons, three sharing with carbon and the other two kept it for itself.

In the second structure, the negative charge of the sulfur is transfered to the nitrogen, meaning that it has 6 electrons the nitrogen (formal charge -1) and carbon and sulfur with 4 and 6 electrons respectively.

Between these two structures, the most stable is the first one basically because Sulfur is a better nucleophile than the Nitrogen, and can form stronger hydrogen bond in acid, giving more stable structure.