Complete Question:
check the first image for complete part of the question
Answer and Explanation:
Epoxide is a three membered ring made up of two carbon atoms and one oxygen atom. Epoxides are cyclic ethers. Due to its ring size, it is highly strained and very reactive. Epoxide ring opening takes place with respect to addition of acid and base.
Ring opening of epoxide with acid:
In the presence of base, the nucleophile attacks the epoxide ring at more substituted site and inverse stereochemistry takes place.(check file 2 attached)
Ring opening of epoxide with base:
The backside attack of nucleophile takes place in less substituted site and then it undergoes protonation to form a product.
(check file 2 attached)
In a combustion of a hydrocarbon compound, 2 reactions are happening per element:
C + O₂ → CO₂
2 H + 1/2 O₂ → H₂O
Thus, we can determine the amount of C and H from the masses of CO₂ and H₂O produced, respectively.
1.) Compute for the amount of C in the compound. The data you need to know are the following:
Molar mass of C = 12 g/mol
Molar mass of CO₂ = 44 g/mol
Solution:
0.5008 g CO₂*(1 mol CO₂/ 44 g)*(1 mol C/1 mol CO₂) = 0.01138 mol C
0.01138 mol C*(12 g/mol) = 0.13658 g C
Compute for the amount of H in the compound. The data you need to know are the following:
Molar mass of H = 1 g/mol
Molar mass of H₂O = 18 g/mol
Solution:
0.1282 g H₂O*(1 mol H₂O/ 18 g)*(2 mol H/1 mol H₂O) = 0.014244 mol H
0.014244 mol H*(1 g/mol) = 0.014244 g H
The percent composition of pure hydrocarbon would be:
Percent composition = (Mass of C + Mass of H)/(Mass of sample) * 100
Percent composition = (0.13658 g + 0.014244 g)/(<span>0.1510 g) * 100
</span>Percent composition = 99.88%
2. The empirical formula is determined by finding the ratio of the elements. From #1, the amounts of moles is:
Amount of C = 0.01138 mol
Amount of H = 0.014244 mol
Divide the least number between the two to each of their individual amounts:
C = 0.01138/0.01138 = 1
H = 0.014244/0.01138 = 1.25
The ratio should be a whole number. So, you multiple 4 to each of the ratios:
C = 1*4 = 4
H = 1.25*4 = 5
Thus, the empirical formula of the hydrocarbon is C₄H₅.
3. The molar mass of the empirical formula is
Molar mass = 4(12 g/mol) + 5(1 g/mol) = 53 g/mol
Divide this from the given molecular weight of 106 g/mol
106 g/mol / 53 g/mol = 2
Thus, you need to multiply 2 to the subscripts of the empirical formula.
Molecular Formula = C₈H₁₀
Answer: 250 kJ
Explanation: According to Hess’s law of constant heat summation, the heat absorbed or evolved in a given chemical equation is the same whether the process occurs in one step or several steps.
According to Hess’s law, the chemical equation can be treated as algebraic expressions and can be added or subtracted to yield the required equation. That means the enthalpy change of the overall reaction is the sum of the enthalpy changes of the intermediate reactions.
(1)
(2)
Net chemical equation:
(3)
Adding 1 and 2 we get,
(4)
Now dividing equation (4) by 4, we get
(4)
Answer:
0.0344 moles and 1.93g.
Explanation:
Molarity is defined as the ratio between moles of a solute (In this case, KOH), and the volume. With molarity and volume we can solve the moles of solute. With moles of solute we can find mass of the solute as follows:
<em>Moles KOH:</em>
15.2mL = 0.0152L * (2.26mol / L) = 0.0344moles
<em>Mass KOH:</em>
0.0344 moles * (56.11g/mol) = 1.93g of KOH
Among the given choices, the right statement is that computers are advantageous because it holds a larger amount of data over graphing calculators. Calculators are easier to transport and has lower power consumption. Answer here is D.
