Sulfonation of benzene has the following mechanism: (1) 2 H2SO4 ⇌ H3O+ + HSO4− + SO3 [fast] (2) SO3 + C6H6 → H(C6H5+)SO3− [slow]
1 answer:
Question is incomplete, complete question is as follows :
Complete Question : .Sulfonation of benzene has the following mechanism:
(1) 2 H2SO4 ⇌ H3O+ + HSO4− + SO3
[fast]
(2) SO3 + C6H6 → H(C6H5+)SO3−
[slow]
(3) H(C6H5+)SO3− + HSO4− → C6H5SO3− + H2SO4
[fast]
(4) C6H5SO3− + H3O+ → C6H5SO3H + H2O
[fast]
write the overall rate law for the initial rate of the reaction as a fraction.
Rate=k(________/_________)
Answer:
The overall rate law for the initial reaction is =
Explanation :
Frist of all, all the common terms are cancelled out and written the overall reaction.
As we know that the rate depednant step is the slowest step of the reaction, rate law is :
rate =
But the problem is that SO3 cannot be written in the overall rate law because it is an intermediate.
Rate law for synthesis of S03 is as follows :
rate =
Hence when we substitute equation 2 in equation one,
Rate comes out to be =
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Answer: The half-reactions represents reduction are as follows.
Explanation:
A half-reaction where addition of electrons take place or a reaction where decrease in oxidation state of an element takes place is called reduction-half reaction.
For example, the oxidation state of Cr in is +6 which is getting converted into +3, that is, decrease in oxidation state is taking place as follows.
Similarly, oxidation state of Mn in is +7 which is getting converted into +2, that is, decrease in oxidation state is taking place as follows.
Thus, we can conclude that half-reactions represents reduction are as follows.
The molarity of formic acid is 100 mM or . The dissociation reaction of formic acid is as follows:
The expression for dissociation constant of the reaction will be:
Rearranging,
Here, pH of solution is 4.15 thus, concentration of hydrogen ion will be:
Similarly, thus,
Putting the values,
Therefore, the concentration of formate will be 0.2511 M.