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RUDIKE [14]
3 years ago
11

Determine the partial negative charge on the bromine atom in a c−br bond. the bond length is 1.93 å and the bond dipole moment i

s 1.40 d . express your answer using 3 significant figures. the partial negative charge on the bromine atom = previous answersrequest answer incorrect; try again; 4 attempts remaining provide feedback.
Chemistry
1 answer:
vaieri [72.5K]3 years ago
3 0

Answer:

The value is x  =  0.151  \ e

Explanation:

From the question we are told that

The bond length is l  =  1.93\  \r  a =  1.93 *1 *10^{-10}  =1.93 *10^{-10}\  m

The bond dipole moment is \mu  = 1.40 d  = 1.40 *  3.33564 *10^{-30}  =  4.6699 *10^{-30} \  C \cdot m

Generally the dipole moment is mathematically represented as

\mu  =  Q *  l

Here Q is the partial negative charge on the bromine atom

So

Q =  \frac{\mu}{ l}

=> Q =  \frac{4.6699 *10^{-30}}{ 1.93 *10^{-10} }

=> Q = 2.42 *10^{-20} C

Generally

1 electronic charge(e) is equivalent to 1.60*10^{-19} C

So x electronic charge(e) is equivalent to Q = 2.42 *10^{-20} C

=> x  =  \frac{2.42 *10^{-20}}{1.60*10^{-19} }

=>     x  =  0.151  \ e

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For Na2HPO4:(( (Note that for H3PO4, ka1= 6.9x10-3, ka2 = 6.4x10-8, ka3 = 4.8x10-13 ) a) The active anion is H2PO4- b) The activ
Komok [63]

Answer:

Check the explanation

Explanation:

Answer – Given, H_3PO_4 acid and there are three Ka values

K_{a1}=6.9x10^8, K_{a2} = 6.2X10^8, and K_{a3}=4.8X10^{13}

The transformation of H_2PO_4- (aq) to HPO_4^2-(aq)is the second dissociation, so we need to use the Ka2 = 6.2x10-8 in the Henderson-Hasselbalch equation.

Mass of KH2PO4 = 22.0 g , mass of Na2HPO4 = 32.0 g , volume = 1.00 L

First we need to calculate moles of each

Moles of KH2PO4 = 22.0 g / 136.08 g.mol-1

                             = 0.162 moles

Moles of Na2HPO4 = 32.0 g /141.96 g.mol-1

                             = 0.225 moles

[H2PO4-] = 0.162 moles / 1.00 L = 0.162 M

[HPO42-] = 0.225 moles / 1.00 L = 0.225 M

Now we need to calculate the pKa2

pKa2 = -log Ka

       = -log 6.2x10-8

       = 7.21

We know Henderson-Hasselbalch equation

pH = pKa + log [conjugate base] / [acid]

pH = 7.21 + log 0.225 / 0.162

     = 7.35

The pH of a buffer solution obtained by dissolving 22.0 g of KH2PO4 and 32.0 g of Na2HPO4 in water and then diluting to 1.00 L is 7.35

6 0
3 years ago
The molar mass is determined by measuring the freezing point depression of an aqueous solution. A freezing point of -5.20°C is r
Dima020 [189]

Answer:

The empirical formula is C2H4O3

The molecular formula is C4H8O6

The molar mass is 152 g/mol

Explanation:

The complete question is: An unknown compound contains only carbon, hydrogen, and oxygen. Combustion analysis of the compound gives mass percents of 31.57% C and 5.30% H. The molar mass is determined by measuring the freezing-point depression of an aqueous solution. A freezing point of -5.20°C is recorded for a solution made by dissolving 10.56 g of the compound in 25.0 g water. Determine the empirical formula, molar mass, and molecular formula of the compound. Assume that the compound is a nonelectrolyte.

Step 1: Data given

Mass % of Carbon = 31.57 %

Mass % of H = 5.30 %

Freezing point = -5.20 °C

10.56 grams of the compound dissolved in 25.0 grams of water

Kf water = 1.86 °C kg/mol

Step 2: Calculate moles of Carbon

Suppose 31.57% = 31.57 grams

moles C = mass C / Molar mass C

moles C = 31.57 grams / 12.0 g/mol = 2.63 moles

Step 3: Calculate moles of Hydrogen:

Moles H = 5.30 grams / 1.01 g/mol

moles H = 5.25 moles

Step 4: Calculate moles of Oxygen

Moles O = ( 100 - 31.57 - 5.30) / 16 g/mol

Moles O = 3.95 moles

Step 5: We divide by the smallest number of moles

C: 2.63 / 2.63 = 1 → 2

H: 5.25/2.63 = 2 → 4

O: 3.95/ 2.63 = 1.5 → 3

The empirical formula is C2H4O3

The molar mass of the empirical formula = 76 g/mol

Step 6: Calculate moles solute

Freezing point depression = 5.20 °C = m * 1.86

m = 5.20 / 1.86

m = 2.80 molal = 2.80 moles / kg

2.80 molal * 0.025 kg = 0.07 moles

Step 7: Calculate molar mass

Molar mass = mass / moles

Molar mass = 10.56 grams / 0.07 moles

Molar mass = 151 g/mol

Step 8: Calculate molecular formula

151 / 76 ≈  2

We have to multiply the empirical formula by 2

2*(C2H4O3) = C4H8O6

The molecular formula is C4H8O6

The molar mass is 152 g/mol

6 0
4 years ago
When does the given chemical system reach dynamic equilibrium?
AVprozaik [17]
Once it becomes balanced. 
7 0
3 years ago
Jennie decides to mix the content of her beaker with another lab group to see “the results.” Is this safe why or why not explain
Ray Of Light [21]

Answer: no

Explanation:

It could be dangerous since you don't know what substance are you adding.it may end up in an explosion

I hope this helps :)

6 0
2 years ago
Draw the Lewis structure for BCl3. How many single bonds, double bonds, triple bonds, and unshared pairs of electrons are on the
andreev551 [17]

Answer :  The number of single bonds, double bonds, triple bonds, and unshared pairs of electrons on the central atom are, 3, 0, 0 and 0 respectively.

Explanation :

Lewis-dot structure : It shows the bonding between the atoms of a molecule and it also shows the unpaired electrons present in the molecule.

In the Lewis-dot structure the valance electrons are shown by 'dot'.

The given molecule is, BCl_3

As we know that boron has '3' valence electrons and chlorine has '7' valence electrons.

Therefore, the total number of valence electrons in BCl_3 = 3 + 3(7) = 24

According to Lewis-dot structure, there are 6 number of bonding electrons and 18 number of non-bonding electrons.

From the Lewis-dot structure we conclude that,

The number of single bonds, double bonds, triple bonds, and unshared pairs of electrons on the central atom are, 3, 0, 0 and 0 respectively.

3 0
4 years ago
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