Answer:
The system makes the transition from nonspontaneous to spontaneous at a temperature of 954.7 K.
Under 954.7 K the reaction is nonspontaneous; more than 954.7 K is the reaction spontaneous.
Explanation:
CH4(g) + 2H2O(g) ⇆ CO2(g) + 4H2(g)
CH4(g) H2O(g) CO2(g) H2(g) ΔH°f (kJ/mol): –74.87 –241.8 –393.5 0
ΔG°f (kJ/mol): –50.81 –228.6 –394.4 0
S°(J/K·mol): 186.1 188.8 213.7 130.7
ΔG<0 to be spontaneous
ΔG = ΔH- TΔS <0
ΔH = ∑nΔH(products) - ∑nΔH(reactant)
ΔH = (-393.5) - (–74.87 + 2*–241.8)
ΔH = 164.97 kJ = 164970 J
ΔS = ∑nΔS(products) - ∑nΔS(reactant)
ΔS = (213.7 + 4*130.7) - (186.1 + 2*188.8)
ΔS = 172.8 J
0 > 164970 J - T* 172.8 J
-164970 J > - T* 172.8 J
954.7< T
The system makes the transition from nonspontaneous to spontaneous at a temperature of 954.7 K.
Under 954.7 K the reaction is nonspontaneous; more than 954.7 K is the reaction spontaneous.
The balanced equation for the reaction is as follows
2H₂ + O₂ --> 2H₂O
stoichiometry of H₂ to O₂ is 2:1
number of H₂ moles - 30.0 g / 2 g/mol = 15 mol
number of O₂ moles - 80.0 g / 32 g/mol = 2.5 mol
limiting reactant is the reagent in which only a fraction is used up in the reaction
if H₂ is the limiting reactant
if 2 mol of H₂ requires 1 mol of O₂
then 15 mol of H₂ requires 1/2 x 15.0 = 7.5 mol of O₂
but only 2.5 mol of O₂ is required
this means that O₂ is the limiting reagentt and H₂ is in excess
Answer:
[H+] = 4.365x10⁻¹¹
Explanation:
The pH is a measurement widely used in chemistry. Is used in quality control to determine if a product is good for human or pet consumption. The equation to obtain the pH is:
pH = -log [H+]
To solve [H+]:
10^pH = -[H+]
10^-pH = -[H+]
In the problem:
10^-10.36 = -[H+]
<h3>[H+] = 4.365x10⁻¹¹</h3>
In ionic bonding, an arrow is often drawn on the diagram to show the direction the electrons move to form the ions.
