How many grams of solid Na2CO3 are required to neutralize exactly 2 liters of an HCI solution of pH 2.0?
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Here we have to draw the four isomers of the compound 3-bromo-4-fluorohexane.
The four isomers of the compound is shown in the figure.
In an organic molecule the chiral -C center is that where four (4) different groups are present. In 3-bromo-4-fluorohexane the 3 and 4 positions are chiral centers. The possible isomers of a molecule can be obtained from the formula 2n. As here 2 chiral centers are present thus number of stereoisomers will be 2×2 = 4.
The four different isomers as shown in the figure are 3R-, 4R-; 3S-, 4S; 3R, 4S and 3S-, 4R- 3-bromo-4-fluorohexane.
In the 3-bromo-4-fluorohexane the functional groups are -Br, C₂H₅, -C₃H₆F and -H for 3-position and -F, -C₂H₅, -C₃H₆ and -H for 4-position respectively.
The priority of the -3 position will be Br > C₃H₆F > C₂H₅ > H and for -4 position F > C₃H₆Br > C₂H₅ > H. If the rotation from the higher priority group to lower is clockwise and anticlockwise then the S- and R- notation are used respectively. However if the -H atom is present at the horizontal position then the notation will be reverse.
Thus the four isomers of the compound is shown.
Explanation:
According to Le Chatelier's principle, any disturbance caused in an equilibrium reaction will shift the equilibrium in a direction that will oppose the change.
As the given reaction is as follows.
(a) When increase the temperature of the reactants or system then equilibrium will shift in forward direction where there is less temperature. It is possible for an endothermic reaction.
Thus, formation of will increase.
- (b) When we decrease the volume (at constant temperature) of given reaction mixture then it implies that there will be increase in pressure of the system. So, equilibrium will shift in a direction where there will be decrease in composition of gaseous phase. That is, in the backward direction reaction will shift.
Hence, formation of will decrease with decrease in volume.
- When we increase the mount of
then equilibrium will shift in the direction of decrease in concentration that is, in the forward direction.
Thus, we can conclude that formation of will increase then.