In this reaction 50% of the compound decompose in 10.5 min thus, it is half life of the reaction and denoted by symbol 
.
(a) For first order reaction, rate constant and half life time are related to each other as follows:
Thus, rate constant of the reaction is 
.
(b) Rate equation for first order reaction is as follows:
![k=\frac{2.303}{t_{1/2}}log\frac{[A_{0}]}{[A_{t}]}](https://tex.z-dn.net/?f=k%3D%5Cfrac%7B2.303%7D%7Bt_%7B1%2F2%7D%7Dlog%5Cfrac%7B%5BA_%7B0%7D%5D%7D%7B%5BA_%7Bt%7D%5D%7D)
now, 75% of the compound is decomposed, if initial concentration ![[A_{0} ]](https://tex.z-dn.net/?f=%5BA_%7B0%7D%20%5D)
is 100 then concentration at time t ![[A_{t} ]](https://tex.z-dn.net/?f=%5BA_%7Bt%7D%20%5D)
will be 100-75=25.
Putting the values,
On rearranging,
Thus, time required for 75% decomposition is 21 min.
Answer:
Demisty = mass/volume = 142/ (2×2×4) = 142 / 16 =
8.875g/cm^3
Explanation:
Answer:
The order of solubility is AgBr < Ag₂CO₃ < AgCl
Explanation:
The solubility constant give us the molar solubilty of ionic compounds. In general for a compound AB the ksp will be given by:
Ksp = (A) (B) where A and B are the molar solubilities = s² (for compounds with 1:1 ratio).
It follows then that the higher the value of Ksp the greater solubilty of the compound if we are comparing compounds with the same ionic ratios:
Comparing AgBr: Ksp = 5.4 x 10⁻¹³ with AgCl: Ksp = 1.8 x 10⁻¹⁰, AgCl will be more soluble.
Comparing Ag2CO3: Ksp = 8.0 x 10⁻¹² with AgCl Ksp = AgCl: Ksp = 1.8 x 10⁻¹⁰ we have the complication of the ratio of ions 2:1 in Ag2CO3, so the answer is not obvious. But since we know that
Ag2CO3 ⇄ 2 Ag⁺ + CO₃²₋
Ksp Ag2CO3 = 2s x s = 2 s² = 8.0 x 10-12
s = 4 x 10⁻12 ∴ s= 2 x 10⁻⁶
And for AgCl
AgCl ⇄ Ag⁺ + Cl⁻
Ksp = s² = 1.8 x 10⁻¹⁰ ∴ s = √ 1.8 x 10⁻¹⁰ = 1.3 x 10⁻⁵
Therefore, AgCl is more soluble than Ag₂CO₃
The order of solubility is AgBr < Ag₂CO₃ < AgCl
