First convert celcius to Kelvin.
20 + 273 = 293K
31 + 273 = 304K
Now we can set up an equation based on the information we have.
V1 = 5
P1 = 365
T1 = 293
V2 = 5
P1 = x
T2 = 304
The equation be:
Now just solve.
1825/293 = 5x/304
Cross multiply.
554800 = 1465x
Divide both sides by 1465
x = 378.7030717 which can then be rounded to 378.7 mmHg
Answer:
<u>D. It will decrease by a factor of 4</u>
Explanation:
According to the question , the equation follows :
Rate law : This states the rate of reaction is directly proportional to concentration of reactants with each reactant raised to some power which may or may not be equal to the stoichiometeric coefficient.
.................(1)
STEP": First, find out the power "a" and "b"
a+b = 3 (because it is given that the reaction follow 3rd order-kinetics)
According to question, <u><em>doubling the concentration of the first reactant causes the rate to increase by a factor of 2 means,</em></u>
r' = 2r if [A'] = 2[A]
Here [B] is uneffected means [B']=[B]
hence new rate =
Put the value of [A'] , [B'] and r' in the above equation:
...........(2)
Divide equation (1) by (2) we , get
Here A and A cancel each other
B and B cancel each other
We get,
1^b = 1 ( power of 1 = 1)
This is possible only when a = 1
We know that : a + b = 3
1 + b = 3
b =3 -1 = 2
b = 2
Hence the rate law becomes :
<u>.............(3)</u>
Look in the question now, it is asked to calculate the concentration of [B],if cut in half
Hence
[B']=1/2[B]
Insert the value of [B'] in equation (3)
............(a)
But
..............(b)
Compare equation (a) and (b) , we get
new rate r' =
<u>r' = 1/4 r</u>