Write the following number in standard notation: 8.66185 × 104.
2 answers:
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0.042 moles of Hydrogen evolved
<h3>Further explanation</h3>Given
I = 1.5 A
t = 1.5 hr = 5400 s
Required
Number of Hydrogen evolved
Solution
Electrolysis of water ⇒ decomposition reaction of water into Oxygen and Hydrogen gas.
Cathode(reduction-negative pole) : 2H₂O(l)+2e⁻ ⇒ H₂(g)+2OH⁻(aq)
Anode(oxidation-positive pole) : 2H₂O(l)⇒O₂(g)+4H⁻(aq)+4e⁻
Total reaction : 2H₂O(l)⇒2H₂(g)+O₂(g)
So at the cathode H₂ gas is produced
Faraday : 1 mole of electrons (e⁻) contains a charge of 96,500 C
Q = i.t
Q = 1.5 x 5400
Q = 8100 C
mol e⁻ = 8100 : 96500 = 0.084
From equation at cathode , mol ratio e⁻ : H₂ = 2 : 1, so mol H₂ = 0.042
Answer:
The structure with the ring flipped is the most stable
Explanation:
We have the trans 1,2 - dimethylcyclohexane. With the wedge/dash structure we could not figure is this form is stable (If we do a comparison with the cis structure). But when we do a chair structure and ring flipped structure, this is easier to look.
The picture attached shows the structures, they are labeled as 1, 2 and 3, according to this problem.
In the chair structure, according to the picture below, you can see that both methyls are heading in the axial positions of the ring (One facing upward and the other downward). This is pretty stable, however, when the methyls are in those positions, the methyl position 1, can undergoes an 1,3 diaxial interactions with the hydrogens atoms (They are not drawn, but still are there), so this interaction makes this structure a little less stable that it can be.
On the other side, the ring flipped structure, we can see that both methyls are in the equatorials positions of the ring, and in these positions, it can avoid the 1,4 diaxial interactions with the hydrogens atoms, making this structure the most stable structure.
Hope this helps
