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Alexeev081 [22]
3 years ago
7

Describe the changes in properties (from metals to nonmetals or from nonmetals to metals) as we move (a) down a periodic group a

nd (b) across the periodic table from left to right.
Chemistry
1 answer:
defon3 years ago
7 0

Answer:

Explanation:

The changes in properties from metals to non-metals on a periodic table can be measured and determined by the metallicity or electropositivity of elements.

Metallicity is a measure of the tendency of atoms of an element to lose electrons.

a.

Down a periodic group, metallicity increases.

b.

Across a period from left to right electropositivity or metallicity decreases.

Metals are found in the left part of periodic table and the most reactive metal sits in the lower left corner. Non-metals are towards the right side of the table.

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vodomira [7]

Answer:

Expression for the change of melting temperature with pressure..> T₂ = T₁exp(-(P₂-P₁)/(3.61x10⁹ Pa), Freezing Point = 0°C

Explanation:

Derivation from state postulate

Using the state postulate, take the specific entropy,  , for a homogeneous substance to be a function of specific volume  and temperature  .

ds = (partial s/partial v)(t) dv + (partial s/partial T)(v) dT

During a phase change, the temperature is constant, so

ds = (partial s/partial v)(T)  dv

Using the appropriate Maxwell relation gives

ds = (partial P/partial T)(v) dv

s(β) – s(aplαha) = dP/dT (v(β) – v(α))

dP/dT = s(β) – s(α)/v(β) – v(α) = Δs/Δv

Here Δs and Δv are respectively the change in specific entropy and specific volume from the initial phase α to the final phase β.

For a closed system undergoing an internally reversible process, the first law is

du = δq – δw = Tds - Pdv

Using the definition of specific enthalpy, h and the fact that the temperature and pressure are constant, we have

du + Pdv = dh Tds,

ds = dh/T,

Δs = Δh/T = L/T

After substitution of this result into the derivative of the pressure, one finds

dp/dT = L/TΔv

<u>This last equation is the Clapeyron equation.</u>

a)

(dP/dT) = dH/TdV => dP/dlnT = dH/dV

=> dP/dlnT = dH/dV = [H(liquid) - H(solid)]/[V(liquid) - V(solid)]

= [335,000 J/kg]/[1000⁻¹ - 915⁻¹ m³/kg]

= -3.61x10⁹ J/m³ = -3.61x10⁹ Pa

=> P₂ = P₁ - 3.61x10⁹ ln(T₂/T₁) Pa

or

T₂ = T₁exp(-(P₂-P₁)/(3.61x10⁹ Pa)

b) if the pressure in Denver is 84.6 kPa:

T₂(freezing) = 273.15exp[-(84,600-100,000)/(3.61x10⁹)]

≅ 273.15 = 0°C T₁(freezing) essentially no change

5 0
3 years ago
Which element experiences greater London dispersion forces
natali 33 [55]
Its d its the only one that makes sense


8 0
3 years ago
Why is sugar considered an organic compound
Sliva [168]
Sugar is considered an organic compound,
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For which of the following elements would the most common ion be expected to have a larger radius than that of its corresponding
Andre45 [30]

<u>Answer:</u> The ion that is expected to have a larger radius than the corresponding atom is chlorine.

<u>Explanation:</u>

There are two types of ions:

  • <u>Cations:</u> They are formed when an atom looses its valence electrons. They are positive ions.
  • <u>Anions:</u> They are formed when an atom gain electrons in its outermost shell. They are negative ions.

For positive ions, the removal of electron increases the nuclear charge for an outermost electron because the outermost electrons are more strongly attracted by the nucleus. So, the effective nuclear charge increases for cations and thus, the size of the cation will be smaller than that of the corresponding atom.

For negative ions, the addition of electron decreases the nuclear charge for an outermost electron because the outermost electrons are less strongly attracted by the nucleus. So, the effective nuclear charge decreases for anions and thus, the size of the anion will be larger than that of the corresponding atom.

For the given options:

<u>Option a:</u> Chlorine

Chlorine gains 1 electron and form Cl^- ion

<u>Option b:</u> Sodium

Sodium looses 1 electron and form Na^+ ion

<u>Option c:</u> Copper

Copper looses 2 electrons and form Cu^{2+} ion

<u>Option d:</u> Strontium

Strontium looses 2 electrons and form Sr^{2+} ion

Hence, the ion that is expected to have a larger radius than the corresponding atom is chlorine.

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evablogger [386]
Volume can be measures in liters
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