Answer:
The dimerization of butadiene to 4-vinylcyclohexene folows second order kinetics and its rate law will be given by :
![R=k[C_4H_6]^2](https://tex.z-dn.net/?f=R%3Dk%5BC_4H_6%5D%5E2)
Explanation:
The rate of the reaction ;
![R=k[C_4H_6]^x](https://tex.z-dn.net/?f=R%3Dk%5BC_4H_6%5D%5Ex)
As given in the question , that graph of time verses ![\frac{1}{[C_4H_6]}](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B%5BC_4H_6%5D%7D)
was linear but plots of ![[C_4H_6]](https://tex.z-dn.net/?f=%5BC_4H_6%5D)
or ![\ln[C_4H_6]](https://tex.z-dn.net/?f=%5Cln%5BC_4H_6%5D)
was curved.
Generally:
Graph of time verses ![[concentration]](https://tex.z-dn.net/?f=%5Bconcentration%5D)
for zero order reaction is linear with negative slope.
Graph of time verses ![\ln [concentration]](https://tex.z-dn.net/?f=%5Cln%20%5Bconcentration%5D)
for secon order reaction is linear with negative slope.
Graph of time verses ![\frac{1}{[concentration]}](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B%5Bconcentration%5D%7D)
for secon order reaction is linear with positive slope.
So, the dimerization of butadiene to 4-vinylcyclohexene folows second order kinetics and its rate law will be given by :
3.54g H2 means you have 3.54 / 2 = 1.77 moles of H2, which means you have 1.77*2 = 3.54 moles of H atom.
Since 1 mole of NH3 has 3 moles of H, so you can produce 3.54 / 3 moles of NH3, which is (3.54/3) * (12+3) = 17.7 grams
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