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The empirical formula of the following compounds 0.903 g of phosphorus combined with 6.99 g of bromine.
<h3>What is empirical formula?</h3>The simplest whole number ratio of atoms in a compound is the empirical formula of a chemical compound in chemistry. Sulfur monoxide's empirical formula, SO, and disulfur dioxide's empirical formula, S2O2, are two straightforward examples of this idea. As a result, both the sulfur and oxygen compounds sulfur monoxide and disulfur dioxide have the same empirical formula.
<h3>How to find the empirical formula?</h3>Convert the given masses of phosphorus and bromine into moles by multiplying the reciprocal of their molar masses. The molar masses of phosphorus and bromine are 30.97 and 79.90 g/mol, respectively.
Moles phosphorus = 0.903 g phosphorus = 0.0293 mol
Moles bromine 6.99 g bromine=0.0875 mol
The preliminary formula for compound is P0.0293Bro.0875. Divide all the subscripts by the subscript with the smallest value which is 0.0293. The empirical formula is P1.00Br2.99 ≈ P₁Br3 or PBr3
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Answer:
All of the above.
Explanation:
In positive deviation from Raoult's Law occur when the vapour pressure of components is greater than what is expected value in Raoult's law.
When a solution is non ideal then it shows positive or negative deviation.
Let two solutions A and B to form non- ideal solutions.let the vapour pressure of component A is and vapour pressure of component B is
.
= Vapour pressure of component A in pure form
= Vapour pressure of component B in pure form
=Mole fraction of component A
=Mole fraction of component B
The interaction between A- B is less than the interaction A- A and B-B interaction.Therefore, the escaping tendency of liquid molecules in mixture is greater than the escaping tendency in pure form.Hence, the vapour pressure of a mixture is greater than the initial value of vapour pressure.
,
Therefore,
Therefore, the enthalpy of mixing is greater than zero and change in volume is greater than zero.
Hence, option a,b,c and d are true.