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lorasvet [3.4K]
2 years ago
13

7. Suppose 1.01 g of iron (III) chloride is placed in a 10.00-mL volumetric flask with a bit of water in it. The flask is shaken

to dissolve the solid and the flask is then filled to the mark. What is the molarity of the final solution?
Chemistry
1 answer:
Nana76 [90]2 years ago
3 0

<u>Answer:</u> The molarity of Iron (III) chloride is 0.622 M.

<u>Explanation:</u>

Molarity is defined as the number of moles present in one liter of solution.  The equation used to calculate molarity of the solution is:

\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}

Or,

\text{Molarity of the solution}=\frac{\text{Mass of solute}\times 1000}{\text{Molar mass of solute}\times \text{Volume of solution (in mL)}}

We are given:

Mass of iron (III) chloride = 1.01 g

Molar mass of iron (III) chloride = 162.2 g/mol

Volume of the solution = 10 mL

Putting values in above equation, we get:

\text{Molarity of Iron (III) chloride}=\frac{1.01g\times 1000}{162.2g/mol\times 10mL}\\\\\text{Molarity of Iron (III) chloride}=0.622M

Hence, the molarity of Iron (III) chloride is 0.622 M.

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Some SbCl5 is allowed to dissociate into SbCl3 and Cl2 at 521 K. At equilibrium, [SbCl5] = 0.195 M, and [SbCl3] = [Cl2] = 6.98×1
Brilliant_brown [7]

Answer:

a) The equilibrium will shift in the right direction.

b) The new equilibrium concentrations after reestablishment of the equilibrium :

[SbCl_5]=(0.370-x) M=(0.370-0.0233) M=0.3467 M

[SbCl_3]=(6.98\times 10^{-2}+x) M=(6.98\times 10^{-2}+0.0233) M=0.0931 M

[Cl_2]=(6.98\times 10^{-2}+x) M=(6.98\times 10^{-2}+0.0233) M=0.0931 M

Explanation:

SbCl_5(g)\rightleftharpoons SbCl_3(g) + Cl_2(g)

a) Any change in the equilibrium is studied on the basis of Le-Chatelier's principle.

This principle states that if there is any change in the variables of the reaction, the equilibrium will shift in the direction to minimize the effect.

On increase in amount of reactant

SbCl_5(g)\rightleftharpoons SbCl_3(g) + Cl_2(g)

If the reactant is increased, according to the Le-Chatlier's principle, the equilibrium will shift in the direction where more product formation is taking place. As the number of moles of SbCl_5 is  increasing .So, the equilibrium will shift in the right direction.

b)

SbCl_5(g)\rightleftharpoons SbCl_3(g) + Cl_2(g)

Concentration of SbCl_5  = 0.195 M

Concentration of SbCl_3  = 6.98\times 10^{-2} M

Concentration of Cl_2  = 6.98\times 10^{-2} M

On adding more [SbCl_5 to 0.370 M at equilibrium :

SbCl_5(g)\rightleftharpoons SbCl_3(g) + Cl_2(g)

Initially

0.370 M         6.98\times 10^{-2}M    

At equilibrium:

(0.370-x)M   (6.98\times 10^{-2}+x)M  

The equilibrium constant of the reaction  = K_c

K_c=2.50\times 10^{-2}

The equilibrium expression is given as:

K_c=\frac{[SbCl_3][Cl_2]}{[SbCl_5]}

2.50\times 10^{-2}=\frac{(6.98\times 10^{-2}+x)M\times (6.98\times 10^{-2}+x)M}{(0.370-x) M}

On solving for x:

x = 0.0233 M

The new equilibrium concentrations after reestablishment of the equilibrium :

[SbCl_5]=(0.370-x) M=(0.370-0.0233) M=0.3467 M

[SbCl_3]=(6.98\times 10^{-2}+x) M=(6.98\times 10^{-2}+0.0233) M=0.0931 M

[Cl_2]=(6.98\times 10^{-2}+x) M=(6.98\times 10^{-2}+0.0233) M=0.0931 M

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Mass of oxygen = Mass of quartz  (SiO_2) - mass of silicon = 5.05g - 2.36 g = 2.69 g

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