Explanation:
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Answer:
Explanation:
1. Calculate the rate constant
The integrated rate law for first order decay is
where
A₀ and A_t are the amounts at t = 0 and t
k is the rate constant
2. Calculate the half-life
Boyle Law says “the pressure of fixed amount of ideal gas which is at constant temperature is
inversely proportional to its volume".<span>
P = 1/V
<span>Where, P is pressure of the ideal gas and V is volume of the ideal gas.</span>
<span>For two situations, this law can be added as;
P</span>₁V₁ = P₂V₂<span>
</span><span>14 lb/in² x V₁ = 70 lb/in² x 500 mL</span><span>
</span><span>V₁ =
2500 mL</span><span>
Hence, the needed volume of atmospheric air = 2500
mL
<span>Here, we made two </span>assumptions. They are,
1. The
atmospheric air acts as ideal gas.
2.
Temperature is a constant.
<span>We didn't convert the units to SI units since
converting volume and pressure are products of two numbers, they will cut off. </span></span></span>
Answer:
kf = 1.16 x 10¹⁸
Explanation:
Step 1: [Ni(H₂O)₆]²⁺ + 1en → [Ni(H₂O)₄(en)]²⁺ ΔG°1 = -42.9 kJmol⁻¹
Step 2: [Ni(H₂O)₄(en)]²⁺ + 1en → [Ni(H₂O)₂(en)₂]²⁺ ΔG°2 = -35.8 kJmol⁻¹
Step 3: [Ni(H₂O)₂(en)₂]²⁺ + 1en → [Ni(en)₃]²⁺ ΔG°3 = -24.3 kJmol⁻¹
________________________________________________________
Overall reaction: [Ni(H₂O)₆]²⁺ + 3en → [Ni(en)₃]²⁺ ΔG°r
ΔG°r = ΔG°1 + ΔG°2 + ΔG°3
ΔG°r = -42.9 - 35.8 - 24.3
ΔG°r = -103.0 kJmol⁻¹
ΔG°r = -RTlnKf
-103,000 Jmol⁻¹ = - 8.31 J.K⁻¹mol⁻¹ x 298 K x lnKf
kf = e ^(-103,000/-8.31x298)
kf = e ^41.59
kf = 1.16 x 10¹⁸
The chemical formula of Iron (III) Sulfide is FeSO3. This element or compound has another name which is <span>ferric sulfide or sesquisulfide.</span>
