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3 years ago

What are dipoles, and what is the difference between a natural dipole and an induced dipole?

Chemistry

1 answer:

Tasya [4]3 years ago

7 0

Answer:

See explanation below.

Explanation:

Dipoles are molecules that have partial charges. It happens because of the difference in electronegativity of the elements. This property is the tendency that the atom has to take the electron to it, so, in the covalent bond, the shared pair of electrons is easily found at the more electronegativity atom, and so, it has a partial negative charge, and the other, a partial positive charge. This is a natural dipole.

If the difference of electronegativity is 0, or extremely close to 0, then the molecule is nonpolar, and so the molecule doesn't have partial charges. But, to be joined together and form the substance, the partial charge must be induced, so it's an induced dipole.

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In a heat engine of 1000 j of heat enters the system and the piston does 500 j of work what is the final internal energy of the

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Answer : The final energy of the system if the initial energy was 2000 J is, 3500 J

Solution :

(1) The equation used is,

$\Delta U=q+w\\\\U_{final}-U_{initial}=q+w$

where,

$U_{final}$ = final internal energy

$U_{initial}$ = initial internal energy

q = heat energy

w = work done

(2) The known variables are, q, w and $U_{initial}$

initial internal energy = $U_{initial}$ = 2000 J

heat energy = q = 1000 J

work done = w = 500 J

(3) Now plug the numbers into the equation, we get

$U_{final}-(2000J)=(1000J)+(500J)$

(4) By solving the terms, we get

$U_{final}-(2000J)=(1000J)+(500J)$

$U_{final}-(2000J)=1500J$

$U_{final}=2000J+1500J$

$U_{final}=3500J$

(5) Therefore, the final energy of the system if the initial energy was 2000 J is, 3500 J

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4 years ago

At 298 K, what is the Gibbs free energy change (ΔG) for the following reaction?

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Answer:

(a). The Gibbs free energy change is 2.895 kJ and its positive.

(b). The Gibbs free energy change is 34.59 J/mole

(c). The pressure is 14924 atm.

(d). The Gibbs free energy of diamond relative to graphite is 4912 J.

Explanation:

Given that,

Temperature = 298 K

Suppose, density of graphite is 2.25 g/cm³ and density of diamond is 3.51 g/cm³.

$\Delta H\ for\ diamond = 1.897 kJ/mol$

$\Delta H\ for\ graphite = 0 kJ/mol$

$\Delta S\ for\ diamond = 2.38 J/(K mol)$

$\Delta S\ for\ graphite = 5.73 J/(K mol)$

(a) We need to calculate the value of $\Delta G$ for diamond

Using formula of Gibbs free energy change

$\Delta G=\Delta H-T\Delta S$

Put the value into the formula

$\Delta G= (1897-0)-298\times(2.38-5.73)$

$\Delta G=2895.3$

$\Delta G=2.895\ kJ$

The Gibbs free energy change is positive.

(b). When it is compressed isothermally from 1 atm to 1000 atm

We need to calculate the change of Gibbs free energy of diamond

Using formula of gibbs free energy

$\Delta S=V\times\Delta P$

$\Delta S=\dfrac{m}{\rho}\times\Delta P$

Put the value into the formula

$\Delta S=\dfrac{12\times10^{-6}}{3.51}\times999\times10130$

$\Delta S=34.59\ J/mole$

(c). Assuming that graphite and diamond are incompressible

We need to calculate the pressure

Using formula of Gibbs free energy

$\beta= \Delta G_{g}+\Delta G+\Delta G_{d}$

$\beta=V(-\Delta P_{g})+\Delta G+V\Delta P_{d}$

$\beta=\Delta P(V_{d}-V_{g})+\Delta G$

Put the value into the formula

$0=\Delta P(\dfrac{12\times10^{-6}}{3.51}-\dfrac{12\times10^{-6}}{2.25})\times10130+2895.3$

$0=-0.0194\Delta P+2895.3$

$\Delta P=\dfrac{2895.3}{0.0194}$

$\Delta P=14924\ atm$

(d). Here, $C_{p}=0$

So, The value of $\Delta H$ and $\Delta S$ at 900 k will be equal at 298 K

We need to calculate the Gibbs free energy of diamond relative to graphite

Using formula of Gibbs free energy

$\Delta G=\Delta H-T\Delta S$

Put the value into the formula

$\Delta G=(1897-0)-900\times(2.38-5.73)$

$\Delta G=4912\ J$

Hence, (a). The Gibbs free energy change is 2.895 kJ and its positive.

(b). The Gibbs free energy change is 34.59 J/mole

(c). The pressure is 14924 atm.

(d). The Gibbs free energy of diamond relative to graphite is 4912 J.

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