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andrew11 [14]
3 years ago
9

A 1.0 m solution of a compound with 2 ionizable groups (pka's = 6.2 and 9.5; 100 ml total) has a ph of 6.8. what are the concent

rations of the relevant acid and conjugate base?
Chemistry
1 answer:
aleksklad [387]3 years ago
3 0

Answer:

[H₂A] = 0.2M

[HA⁻] = 0.8M

Explanation:

A compound with 2 ionizable groups has as equilbriums:

H₂A ⇄ HA⁻ + H⁺ ⇄ A²⁻ + H⁺

A pH of 6.8 is near to the first equilibrium:

H₂A ⇄ HA⁻ + H pKa = 6.2

To determine concentrations of the acid H₂A and conjugate base HA⁻ we use H-H equation:

pH = pKA + log [HA⁻] / [H₂A]

6.8 = 6.2 + log [HA⁻] / [H₂A]

0.6 = log [HA⁻] / [H₂A]

3.981 = [HA⁻] / [H₂A] <em>(1)</em>

As concentration of the buffer is 1.0M:

1M = [HA⁻] + [H₂A] <em>(2)</em>

Replacing (2) in (1):

3.981 = 1- [H₂A] / [H₂A]

3.981[H₂A] = 1 - [H₂A]

4.981 [H₂A] = 1

[H₂A] = 0.2M

And [HA] = 1M - 0.2M = 0.8M

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5 0
2 years ago
Part a use these data to calculate the heat of hydrogenation of buta-1,3-diene to butane. c4h6(g)+2h2(g)→c4h10(g)
Reptile [31]

<u>Answer:</u> The heat of hydrogenation of the reaction is coming out to be 234.2 kJ.

<u>Explanation:</u>

Enthalpy change is defined as the difference in enthalpies of all the product and the reactants each multiplied with their respective number of moles. It is represented as \Delta H

The equation used to calculate enthalpy change is of a reaction is:

\Delta H_{rxn}=\sum [n\times \Delta H_{(product)}]-\sum [n\times \Delta H_{(reactant)}]

For the given chemical reaction:

C_4H_6(g)+2H_2(g)\rightarrow C_4H_{10}(g)

The equation for the enthalpy change of the above reaction is:

\Delta H_{rxn}=[(1\times \Delta H_{(C_4H_{10})})]-[(1\times \Delta H_{(C_4H_6)})+(2\times \Delta H_{(H_2)})]

We are given:

\Delta H_{(C_4H_{10})}=-2877.6kJ/mol\\\Delta H_{(C_4H_6)}=-2540.2kJ/mol\\\Delta H_{(H_2)}=-285.8kJ/mol

Putting values in above equation, we get:

\Delta H_{rxn}=[(1\times (-2877.6))]-[(1\times (-2540.2))+(2\times (-285.8))]\\\\\Delta H_{rxn}=234.2J

Hence, the heat of hydrogenation of the reaction is coming out to be 234.2 kJ.

4 0
3 years ago
In which 2 states of matter can a substance take the shape of its container?
Natasha2012 [34]

Answer:

solid and liquid

Explanation:

5 0
3 years ago
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For the reaction below, complete the rate expression that relates the change in concentration with respect to time to the rate o
Ann [662]

Answer: Rate in terms of disappearance of NO = -\frac{1d[NO]}{2dt}

Rate in terms of disappearance of Cl_2= -\frac{1d[Cl_2]}{1dt}

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Explanation:

Rate law says that rate of a reaction is directly proportional to the concentration of the reactants each raised to a stoichiometric coefficient determined experimentally called as order.

2NO+Cl_2\rightarrow 2NOCl

The rate in terms of reactants is given as negative as the concentration of reactants is decreasing with time whereas the rate in terms of products is given as positive as the concentration of products is increasing with time.

Rate in terms of disappearance of  = -\frac{1d[NO]}{2dt}

Rate in terms of disappearance of = -\frac{1d[Cl_2]}{1dt}

Rate in terms of appearance of NOCl = +\frac{1d[NOCl]}{2dt}

5 0
3 years ago
A gas occupies a volume of 2.45 L at a pressure of 1.03 atm. What volume will the
Gemiola [76]

Answer:

2.58 L

Explanation:

Please see the step-by-step solution in the picture attached below.

Hope this answer can help you. Have a nice day!

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