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2 years ago

If the 3d and 4s bands overlap in a metal atom, what is the maximum number of electrons for this composite band

Chemistry

1 answer:

kolezko [41]2 years ago

8 0

Answer: 12 electrons

If the 3d and 4s bands are superimposed on a metal atom, the maximum number of electrons for this band will be 12 electrons. Remember that in layer 10 you can enter up to 10 electrons in the orbitals that you have, while the s can enter 2, therefore the amount of electrons that will enter the set formed by both bands when superimposed will be 12 electrons

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2 years ago

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Write a balanced equation for the combustion of C7H16(l) (heptane) -- i.e. its reaction with O2(g) forming the products CO2(g) a

JulsSmile [24]

Answer:

The standard enthalpy of reaction = -4854.7kJ

The difference: ΔH-ΔE = Δ(PV) = Δn.R.T = 9910.288 J ≈ 9.91 kJ

Explanation:

The balanced chemical equation for the combustion of heptane:

C₇H₁₆ (l) + 11 O₂ (g) → 7 CO₂ (g) + 8 H₂O (l)

Given: The standard enthalpy of formation ( $\Delta H _{f}^{\circ }$ ) for: C₇H₁₆ (l) = -187.8 kJ/mol, O₂ (g) = 0 kJ/mol, CO₂ (g) = -393.5 kJ/mol, H₂O (l) = -286 kJ/mol

To calculate the standard enthalpy of reaction ( $\Delta H _{r}^{\circ }$ ) can be calculated by the Hess's law:

$\Delta H _{r}^{\circ } = \left [\sum \nu \cdot\Delta H _{f}^{\circ }(products) \right ] - \left [\sum \nu\cdot\Delta H _{f}^{\circ }(reactants) \right ]$

Here, $\nu$ is the stoichiometric coefficient

⇒ $\Delta H _{r}^{\circ } =$

$\left [ 7\times \Delta H _{f}^{\circ }\left (CO_{2}\right )+ 8\times \Delta H _{f}^{\circ }\left (H_{2}O \right )\right ]$

$- \left [1\times \Delta H _{f}^{\circ }\left (C_{7}H_{16}\right ) +11\times \Delta H _{f}^{\circ }\left (O_{2} \right ) \right ]$

$=\left [ 7\times \left (-393.5 kJ/mol \right )+ 8\times \left (-286 kJ/mol \right )\right ]$

$-\left [1\times \left (-187.8 kJ/mol \right ) +11\times \left (0 kJ/mol \right ) \right ]$

⇒ $\Delta H _{r}^{\circ } = \left [ \left (-2754.5 \right )+ \left (-2288 \right )\right ]\left -[ \left (-187.8 \right ) +\left (0 \right )\right ]$

⇒ $\Delta H _{r}^{\circ } = \left [ -5042.5 ]\left -[ -187.8] = \left ( -4854.7kJ \right )$

To calculate the difference: ΔH-ΔE=Δ(PV)

We use the ideal gas equation: P.V = n.R.T

⇒ ΔH-ΔE=Δ(PV) = Δn.R.T

Given: Temperature:T = 298K, R = 8.314 J⋅K⁻¹⋅mol⁻¹

Δn = number of moles of gaseous products - number of moles of gaseous reactants = (7)- (11) = (-4)

⇒ ΔH-ΔE=Δ(PV) = Δn.R.T = (-4 mol) × (8.314 J⋅K⁻¹⋅mol⁻¹) × (298K) = 9910.288 J = 9.91 kJ (∵ 1 kJ = 1000J )

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3 years ago

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Fiesta28 [93]

Heat= latent heat of fusion+sensible heat+ latent heat of vapourization
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3 years ago