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3 years ago

The following mechanism has been proposed for the gas-phase reaction of chloroform (CHCl3) and chlorine:

Chemistry

1 answer:

shusha [124]3 years ago

3 0

Answer:

Overall reaction equation is:

Cl2(g) + CHCl3(g) --> HCl(g) + CCl4(g)

The intermediates are Cl(g), CCl3(g).

Rate law= ka^1/2 c

Explanation:

This reaction is a non elementary reaction. A non elementary reaction is one that does not take place in a single reactive encounter. In other words, the reaction is comprised of many steps.

The overall reaction equation is the sum of all the reaction steps after all intermediates have been cancelled out. The rate law is obtained from the slowest step in the reaction sequence.

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Learn how changes in binding free energy affect binding and the ratio of unbound and bound molecules.

Delvig [45]

C)[D]/[ED] = 5.20

D)[D]/[ED] = 5.20

E)[D']_T = 1.495* 10 ^-7 M

F)[D'] / [ED'] = 0.0579

Explanation:

E = 250 nM =2.5* 10 ^-7 mol/L , T=298.15 K

Dissociation constant of K_D = 1.3 μM (1.3 *10 ^-6 M)

E + D ⇄ ED → K_a = [ED] / [D][E] (association constant)

ED ⇄ E + D → K_D = [E][D] / [ED] (dissociation constant)

[E] =2.5*10^-7 mol/L

K_D = 1.3* 10^-6 M

K_D = [E][D] / [ED] → [D]/[ED] = K_D / [E]

= [D]/[ED] = 1.3* 10 ^-6 / 2.5 *10^-7

= 13/25 * 10

=130/25 = 5.20

[D]/[ED] = 5.20

ΔG =RTln Kd

ΔG_2 for E and D = 1.987 * 298.15 * ln 1.3*10^-6

ΔG_2 592.454 * [ln 1.3 +ln 10^-6]

ΔG_1 = 592.424 [0.2623 - 13.8155]

ΔG_2 = -592.424 * 13.553

ΔG_1 = -8184.633 cal/ mol

ΔG_1 = -8184.633 * 4.18 J/mol = -34244.508 J?mol

ΔG_1 = -34.245 KL/mol

so, ΔG_2 = ΔG_1 - 10.5 KJ/mol

ΔG_2 = -34.245 - 10.5

ΔG_2 = -44.745KJ / mol

ΔG_2 =RT ln K_D

-44.745 *10^3

=8.314 *298.15 lnK_D

lnK_D' = - 44745 / 2478.81 g

ln K_D' = -18.051

K_D' = -18.051

K_D' = e^-18.051

[D]/[ED] = 5.20

[E] = 2.5* 10 ^-7 mol/ L = a

K_D' = [E][D] / [ED'] E +D' → ED'

K_D' = a/2(x-(a/2) / (a/2)

KD' = x - a/2

=2.447 *10^-8 = (2.5/2) * 10^-7

x=2.447 * 10^-8 + 1.25 * 10^-7

x = 2.447 *10^-8 + 1.25 * 10 ^-7

x= 10^-7 [1.25 + 0.2447]

x = 1.4947 * 10^-7

[D']_T = 1.495* 10 ^-7 M

K_D' = [E][D'] / [ED']

[D'] / [ED'] = KD' / [E]

[D'] / [ED'] = 1.447 *10^-8 / 2.5* 10^-7

[D'] / [ED'] = 0.5788 * 10^-1

[D'] / [ED'] = 0.0579

5 0

3 years ago

Which of the following would increase the strength of an electromagnet? Check all that apply.

TiliK225 [7]

Answer: The correct statements are ; A and B.

Explanation:

The strength of the magnetic field(B) in an electromagnet can be calculated using formula:

$B=\mu\frac{N}{L}I$

$\mu$ = Relative permeability

N = number of turns

I = Current in the wire of the solenoid

L = length of the solenoid or electromagnetic

As we can see from the formula:

$B\propto N$

$B\propto I$

So, by increasing the turns and increasing current flowing through wire one can increase the strength of an electromagnet.

Hence, the correct statements are ; A and B.

5 0

2 years ago

15 POINTS PLEASE HELP What volume of water must be added to 35mL of 2.6m KCl to reduce its concentration to 1.2m? Please explain

BartSMP [9]

First, find the volume the solution needs to be diluted to in order to have the desired molarity:
You have to use the equation M₁V₁=M₂V₂ when ever dealing with dilutions.

M₁=the starting concentration of the solution (in this case 2.6M)
V₁=the starting volume of the solution (in this case 0.035L)
M₂=the concentration we want to dilute to (in this case 1.2M)
V₂=the volume of solution needed for the dilution (not given)

Explaining the reasoning behind the above equation:
MV=moles of solute (in this case KCl) because molarity is the moles of solute per Liter of solution so by multiplying the molarity by the volume you are left with the moles of solute. The moles of solute is a constant since by adding solvent (in this case water) the amount of solute does not change. That means that M₁V₁=moles of solute=M₂V₂ and that relationship will always be true in any dilution.

Solving for the above equation:
V₂=M₁V₁/M₂
V₂=(2.6M×0.035L)/1.2M
V₂=0.0758 L
That means that the solution needs to be diluted to 75.8mL to have a final concentration of 1.2M.

Second, Finding the amount of water needed to be added:
Since we know that the volume of the solution was originally 35mL and needed to be diluted to 75.8mL to reach the desired molarity, to find the amount of solvent needed to be added all you do is V₂-V₁ since the difference in the starting volume and final volume is equal to the volume of solvent added.
75.8mL-35mL=40.8mL
40.8mL of water needs to be added

I hope this helps. Let me know if anything is unclear.
Good luck on your quiz!

5 0

3 years ago

Just wanted to make sure I have the right idea.

Rasek [7]

Explanation:

yes you got the right idea

4 0

3 years ago

What is the process by which sand dunes occur?

Arte-miy333 [17]

B............................................................................

3 0

3 years ago