I want to say addition. But I have a tendency to be wrong
Answer:
See explaination
Explanation:
please kindly see attachment for the step by step solution of the given problem.
Answer:
-177.9 kJ.
Explanation:
Use Hess's law. Ca(s) + CO2(g) + 1/2O2(g) → CaCO3(s) ΔH = -812.8 kJ 2Ca(s) + O2(g) → 2CaO(s) ΔH = -1269.8 kJ We need to get rid of the Ca and O2 in the equations, so we need to change the equations so that they're on both sides so they "cancel" out, similar to a system of equations. I changed the second equation. Ca(s) + CO2(g) + 1/2O2(g) → CaCO3(s) ΔH = -812.8 kJ 2CaO(s) → 2Ca(s) + O2(g) ΔH = +1269.8 kJ The sign changes in the second equation above since the reaction changed direction. Next, we need to multiply the first equation by two in order to get the coefficients of the Ca and O2 to match those in the second equation. We also multiply the enthalpy of the first equation by 2. 2Ca(s) + 2CO2(g) + O2(g) → 2CaCO3(s) ΔH = -1625.6 kJ 2CaO(s) → 2Ca(s) + O2(g) ΔH = +1269.8 kJ Now we add the two equations. The O2 and 2Ca "cancel" since they're on opposite sides of the arrow. Think of it more mathematically. We add the two enthalpies and get 2CaO(s) + 2CO2(g) → 2CaCO3(s) and ΔH = -355.8 kJ. Finally divide by two to get the given equation: CaO(s) + CO2(g) → CaCO3(s) and ΔH = -177.9 kJ.
Answer:
A mixture of 100. mL of 0.1 M HC3H5O3 and 50. mL of NaOH
Explanation:
The pH of a buffer solution is calculated using following relation
Thus the pH of buffer solution will be near to the pKa of the acid used in making the buffer solution.
The pKa value of HC₃H₅O₃ acid is more closer to required pH = 4 than CH₃NH₃⁺ acid.
pKa = -log [Ka]
For HC₃H₅O₃
pKa = 3.1
For CH₃NH₃⁺
pKa = 10.64
pKb = 14-10.64 = 3.36 [Thus the pKb of this acid is also near to required pH value)
A mixture of 100. mL of 0.1 M HC3H5O3 and 50. mL of NaOH
Half of the acid will get neutralized by the given base and thus will result in equal concentration of both the weak acid and the salt making the pH just equal to the pKa value.
