The empirical formula : C₁₂H₄F₇
The molecular formula : C₂₄H₈F₁₄
<h3>Further explanation</h3>mol C (MW=12 g/mol)
mol H(MW=1 g/mol) :
mol F(MW=19 g/mol)
mol ratio of C : H : O =1.52 : 0.51 : 0.89=3 : 1 : 1.75=12 : 4 : 7
Empirical formula : C₁₂H₄F₇
(Empirical formula)n=molecular formula
( C₁₂H₄F₇)n=562 g/mol
(12.12+4.1+7.19)n=562
(281)n=562⇒ n =2
Molecular formula : C₂₄H₈F₁₄
Answer:
The answer is quartet 2.40 ppm.
Note: Kindly find an attached image below for the part of the solution to this question
Sources: The image was researched from Course hero platform
Explanation:
Solution
Multiplicity or (n+1) rule:
It helps in determination of multiplicity of an individual proton or individual types of proton which are available in the molecule.
Multiplicity =(n+1)
Thus
The non equivalent protons which are attached from adjacent atom is denoted by n.
Now because there are three non-equivalent protons are present at adjacent carbon of methylene group, hence the multiplicity of methylene hydrogen is given as follows:
The multiplicity will be the same for the two hydrogen's. thus we compute multiplicity only for one hydrogen atom stated below:
Non- equivalent = 3
Multiplicity = (3 +1)
= 4
= Quartet for 2H
A quartet for 2H indicates that the hydrogen atoms attached from the carbon, which is attached one side from a methyl group and the other side form an atom that have no any hydrogens.
Now due +I effect of carbonyl group, chemical shift value is high for these two hydrogens which is exactly at 2.40 ppm or 2.40 Quartet.
