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poizon [28]
3 years ago
5

2. A sample of table sugar (sucrose, C12H22O11) has a mass of 1.202 g.

Chemistry
1 answer:
nexus9112 [7]3 years ago
7 0

Answer:

a) \text{no of moles}=\frac{\text{given mass}}{\text{Molecular mass}}

\text{no of moles of sucrose}=\frac{1.202g}{342g/mol}=0.0035moles

b) Moles of carbon in 1 mole of sucrose C_{12}H_{22}O_{11}= 12 moles

Moles of carbon in  0.0035 moles of sucrose C_{12}H_{22}O_{11}=\frac{12}{1}\times 0.0035=0.042moles

Moles of hydrogen in 1 mole of sucrose C_{12}H_{22}O_{11}= 22 moles

Moles of hydrogen in  0.0035 moles of sucrose C_{12}H_{22}O_{11}=\frac{22}{1}\times 0.0035=0.077moles

Moles of oxygen in 1 mole of sucrose C_12H_22O_11= 11 moles

Moles of oxygen in  0.0035 moles of sucrose C_{12}H_{22}O_{11}=\frac{11}{1}\times 0.0035=0.042moles

c)  1 mole of carbon contains =6.023\times 10^{23}atoms

0.042 moles of carbon contain =\frac{6.023\times 10^{23}}{1}\times 0.042=0.25\times 10^{23}atoms

1 mole of hydrogen contains =6.023\times 10^{23}atoms

0.077 moles of hydrogen contain =\frac{6.023\times 10^{23}}{1}\times 0.077=0.46\times 10^{23}atoms

1 mole of oxygen contains =6.023\times 10^{23}atoms

0.042 moles of oxygen contain =\frac{6.023\times 10^{23}}{1}\times 0.042=0.25\times 10^{23}atoms



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Answer:

The correct answer is 199.66 grams per mole.

Explanation:

Based on law of effusion given by Graham, a gas rate of effusion is contrariwise proportionate to the square root of molecular mass, that is, rate of effusion of gas is inversely proportional to the square root of mass. Therefore,  

R1/R2 = √ M2/√ M1

Here rate is the rate of effusion of the gas expressed in terms of number of mole per uni time or volume, and M is the molecular mass of the gas.  

Rate Q/Rate N2 = √M of N2/ √M of Q

The molecular mass of N2 or nitrogen gas is 28 grams per mole and M of Q is molecular mass of Q and based on the question Q needs 2.67 times more to effuse in comparison to nitrogen gas, therefore, rate of Q = rate of N2/2.67

Now putting the values we get,  

rate of N2/2.67/rate of N2 = √28/ √M of Q

√M of Q = √ 28 × 2.67

M of Q = (√ 28 × 2.67)²

M of Q = 199.66 grams per mole

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a) Whatis the composition in mole fractions of a solution of benzene and toluene that has a vapor pressure of 35 torr at 20 °C?
iogann1982 [59]

Answer:

molar composition for liquid

xb= 0.24

xt=0.76

molar composition for vapor

yb=0.51

yt=0.49

Explanation:

For an ideal solution we can use the Raoult law.

Raoult law: in an ideal liquid solution, the vapor pressure for every component in the solution (partial pressure) is equal to the vapor pressure of every pure component multiple by its molar fraction.  

For toluene and benzene would be:

P_{B}=x_{B}*P_{B}^{o}

P_{T}=x_{T}*P_{T}^{o}

Where:

P_{B} is partial pressure for benzene in the liquid  

x_{B} is benzene molar fraction in the liquid  

P_{B}^{o} vapor pressure for pure benzene.  

The total pressure in the solution is:

P= P_{T}+ P_{B}

And  

1=x_{B}+x_{T}

Working on the equation for total pressure we have:

P=x_{B}*P_{B}^{o} + x_{T}*P_{T}^{o}

Since x_{T}=1-x_{B}

P=x_{B}*P_{B}^{o} + (1-x_{B})*P_{T}^{o}

We know P and both vapor pressures so we can clear x_{B} from the equation.

x_{B}=\frac{P- P_{T}^{o}}{ P_{B}^{o} - P_{T}^{o}}

x_{B}=\frac{35- 22}{75-22} = 0.24

So  

x_{T}=1-0.24 = 0.76

To get the mole fraction for the vapor we know that in the equilibrium:

P_{B}=y_{B}*P

y_{T}=1-y_{B}

So  

y_{B} =\frac{P_{B}}{P}=\frac{ x_{B}*P_{B}^{o}}{P}

y_{B}=\frac{0.24*75}{35}=0.51

y_{T}=1-0.51=0.49

Something that we can see in these compositions is that the liquid is richer in the less volatile compound (toluene) and the vapor in the more volatile compound (benzene). If we take away this vapor from the solution, the solution is going to reach a new state of equilibrium, where more vapor will be produced. This vapor will have a higher molar fraction of the more volatile compound. If we do this a lot of times, we can get a vapor that is almost pure in the more volatile compound. This is principle used in the fractional distillation.

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