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zubka84 [21]
3 years ago
13

g If a small amount of a strong acid is added to a buffer made up of a weak acid, HA, and the sodium salt of its conjugate base,

NaA, the pH of the buffer solution does not change appreciably because
Chemistry
1 answer:
ikadub [295]3 years ago
5 0

Answer:

Explanation is in the answer

Explanation:

The pH of the buffer solution does not change appreciably because the strong acid (free H⁺) reacts with conjugate base of buffer producing more weak acid. pH formula of buffers is (Henderson-Hasselbalch formula):

pH = pKa + log ( [A⁻] / [HA] )

The addition of strong acid decreases [A⁻] increasing [HA]. pH change just in the log of the ratio of [A⁻] with [HA], that is a real little effect over pH of the buffer solution.

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Calculate delta Gº for the following system:
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Answer:

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Explanation:

Data Given

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The answer will be calculated by the following equation for the Gibbs free energy

                    G = H - TS

Where

G = Gibbs free energy

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So the change in the Gibbs free energy at constant temperature can be written as

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ΔS = Change in entropy

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put values in equation 1

                  ΔG = (-472 kJ/mol) - 273.15 K (-0.108 KJ/mol K)

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                 ΔG = - 442.5  KJ/mol          

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