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Dmitry_Shevchenko [17]
3 years ago
8

A 25.0 g sample of an alloy was heated to 100.0 oC and dropped into a beaker containing 90 grams of water at 25.32 oC. The tempe

rature of the water rose to a final value of 27.18 oC. Neglecting heat losses to the room and the heat capacity of the beaker itself, what is the specific heat of the alloy
Chemistry
1 answer:
kaheart [24]3 years ago
6 0

Answer:

The specific heat of the alloy C_{a} = 0.37 \frac{KJ}{Kg K}

Explanation:

Mass of an alloy m_{a} = 25 gm

Initial temperature T_{a} = 100°c = 373 K

Mass of water m_{w} = 90 gm

Initial temperature of water T_{w} = 25.32 °c = 298.32 K

Final temperature T_{f} = 27.18 °c = 300.18 K

From energy balance equation

Heat lost by alloy = Heat gain by water

m_{a} C_{a}  [T_{a} - T_{f}] = m_{w} C_w (T_{f} -T_{w} )

25 × C_{a} × ( 373 - 300.18 ) = 90 × 4.2 (300.18 - 298.32)

C_{a} = 0.37 \frac{KJ}{Kg K}

This is the specific heat of the alloy.

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OverLord2011 [107]

Answer:

ΔpH = 0.296

Explanation:

The equilibrium of acetic acid (CH₃COOH) in water is:

CH₃COOH ⇄ CH₃COO⁻ + H⁺

Henderson-Hasselbalch formula to find pH in a buffer is:

pH = pKa + log₁₀ [CH₃COO⁻] / [CH₃COOH]

Replacing with known values:

5.000 = 4.740 + log₁₀ [CH₃COO⁻] / [CH₃COOH]

0.260 =  log₁₀ [CH₃COO⁻] / [CH₃COOH]

1.820 = [CH₃COO⁻] / [CH₃COOH] <em>(1)</em>

As total molarity of buffer is 0.100M:

[CH₃COO⁻] + [CH₃COOH] = 0.100M <em>(2)</em>

Replacing (2) in (1):

1.820 = 0.100M - [CH₃COOH] / [CH₃COOH]

1.820[CH₃COOH] = 0.100M - [CH₃COOH]

2.820[CH₃COOH] = 0.100M

[CH₃COOH] = 0.100M / 2.820

[CH₃COOH] = <em>0.035M</em>

Thus: [CH₃COO⁻] = 0.100M - 0.035M = <em>0.065M</em>

5.40 mL of a 0.490 M HCl are:

0.0054L × (0.490mol / L) = 2.646x10⁻³ moles HCl.

Moles of CH₃COO⁻ are: 0.155L × (0.065mol / L) = 0.0101 moles

HCl reacts with CH₃COO⁻ thus:

HCl + CH₃COO⁻ → CH₃COOH

After reaction, moles of CH₃COO⁻ are:

0.0101 moles - 2.646x10⁻³ moles = <em>7.429x10⁻³ moles of CH₃COO⁻</em>

<em />

Moles of CH₃COOH  before reaction are: 0.155L × (0.035mol / L) = 5.425x10⁻³ moles of CH₃COOH. As reaction produce 2.646x10⁻³ moles of CH₃COOH, final moles are:

5.425x10⁻³ moles +  2.646x10⁻³ moles = <em>8.071x10⁻³ moles of CH₃COOH</em>. Replacing these values in Henderson-Hasselbalch formula:

pH = 4.740 + log₁₀ [7.429x10⁻³ moles] / [8.071x10⁻³ moles]

pH = 4.704

As initial pH was 5.000, change in pH is:

ΔpH = 5.000 - 4.740 = <em>0.296</em>

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How GM food are produced?​
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Answer:

d. Sum of product enthalpies minus the sum of reactant enthalpies

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