Answer : The balanced equations will be:
Explanation :
The general rate of reaction is,
Rate of reaction : It is defined as the change in the concentration of any one of the reactants or products per unit time.
The expression for rate of reaction will be :
![\text{Rate of disappearance of A}=-\frac{1}{a}\frac{d[A]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20disappearance%20of%20A%7D%3D-%5Cfrac%7B1%7D%7Ba%7D%5Cfrac%7Bd%5BA%5D%7D%7Bdt%7D)
![\text{Rate of disappearance of B}=-\frac{1}{b}\frac{d[B]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20disappearance%20of%20B%7D%3D-%5Cfrac%7B1%7D%7Bb%7D%5Cfrac%7Bd%5BB%5D%7D%7Bdt%7D)
![\text{Rate of formation of C}=+\frac{1}{c}\frac{d[C]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20formation%20of%20C%7D%3D%2B%5Cfrac%7B1%7D%7Bc%7D%5Cfrac%7Bd%5BC%5D%7D%7Bdt%7D)
![\text{Rate of formation of D}=+\frac{1}{d}\frac{d[D]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20formation%20of%20D%7D%3D%2B%5Cfrac%7B1%7D%7Bd%7D%5Cfrac%7Bd%5BD%5D%7D%7Bdt%7D)
![Rate=-\frac{1}{a}\frac{d[A]}{dt}=-\frac{1}{b}\frac{d[B]}{dt}=+\frac{1}{c}\frac{d[C]}{dt}=+\frac{1}{d}\frac{d[D]}{dt}](https://tex.z-dn.net/?f=Rate%3D-%5Cfrac%7B1%7D%7Ba%7D%5Cfrac%7Bd%5BA%5D%7D%7Bdt%7D%3D-%5Cfrac%7B1%7D%7Bb%7D%5Cfrac%7Bd%5BB%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7B1%7D%7Bc%7D%5Cfrac%7Bd%5BC%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7B1%7D%7Bd%7D%5Cfrac%7Bd%5BD%5D%7D%7Bdt%7D)
From this we conclude that,
In the rate of reaction, A and B are the reactants and C and D are the products.
a, b, c and d are the stoichiometric coefficient of A, B, C and D respectively.
The negative sign along with the reactant terms is used simply to show that the concentration of the reactant is decreasing and positive sign along with the product terms is used simply to show that the concentration of the product is increasing.
Now we have to determine the balanced equations corresponding to the following rate expressions.
![Rate=-\frac{d[CH_4]}{dt}=-\frac{1}{2}\frac{d[O_2]}{dt}=+\frac{1}{2}\frac{d[H_2O]}{dt}=+\frac{d[CO_2]}{dt}](https://tex.z-dn.net/?f=Rate%3D-%5Cfrac%7Bd%5BCH_4%5D%7D%7Bdt%7D%3D-%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BO_2%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7B1%7D%7B2%7D%5Cfrac%7Bd%5BH_2O%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7Bd%5BCO_2%5D%7D%7Bdt%7D)
The balanced equations will be:
Answer:
The final temperature of water is 54.5 °C.
Explanation:
Given data:
Energy transferred = 65 Kj
Mass of water = 450 g
Initial temperature = T1 = 20 °C
Final temperature= T2 = ?
Solution:
First of all we will convert the heat in Kj to joule.
1 Kj = 1000 j
65× 1000 = 65000 j
specific heat of water is 4.186 J /g. °C
Formula:
q = m × c × ΔT
ΔT = T2 - T1
Now we will put the values in Formula.
65000 j = 450 g × 4.186 J /g. °C × (T2 - 20°C )
65000 j = 1883.7 j /°C × (T2 - 20°C )
65000 j/ 1883.7 j /°C = T2 - 20°C
34.51 °C = T2 - 20°C
34.51 °C + 20 °C = T2
T2 = 54.5 °C
You are given
200 grams of H2O(s) at an initial temperature of 0°C. you are also given the
final temperature of water after heating at 65°C. You are required to get the
total amount of heat to melt the sample. The specific heat capacity, cp, of
water is 4.186 J/g-°C. Let us say that T1 = 0°C and T2 = 65°C. The equation for
heat, Q, is
Q = m(cp)(T2-T1)
Q = 200g(4.186
J/g-°C )(65°C - 0°C)
<u>Q =
54,418J</u>
Answer:
The correct answer should be 12.72 pH of the mixed solution and 9.94g mass of solid BASO4 formed.
Explanation:
The molecules of Ba(OH)2 are : 1.00M x 0.05L = 0.05 ( moles )
The molecules of H2SO4 are : 0.494M x 0.0864L = 0.0426816
Ba(OH)2 + H2SO4 ----> BaSO4 + 2 H2O
0.0426816<--- 0.0426816
The mixed solution is Ba(OH)2 with 0.05 - 0.0426816 = 0.0073184
The concentration of mixed solution is : 0.0073184 : ( 0.05 + 0.0864 ) = 0.054 M
The pH of mixed solution is 14 - -log[0.054] = 14 - 1.27 = 12.73 PH
And the mass of BaSO4 is 0.0426816 x ( 137 + 32 + 16 x 4 ) = 9.94 gams.
