Answer:
6.5 × 10¹⁵/ cm³
Explanation:
Thinking process:
The relation
With the expression Ef - Ei = 0.36 × 1.6 × 10⁻¹⁹
and ni = 1.5 × 10¹⁰
Temperature, T = 300 K
K = 1.38 × 10⁻²³
This generates N₀ = 1.654 × 10¹⁶ per cube
Now, there are 10¹⁶ per cubic centimeter
Hence,
Answer:
(a)
<em>d</em>Q = m<em>d</em>q
<em>d</em>q = <em>d</em>T
=
(T₂ - T₁)
From the above equations, the underlying assumption is that remains constant with change in temperature.
(b)
Given;
V = 2L
T₁ = 300 K
Q₁ = 16.73 KJ , Q₂ = 6.14 KJ
ΔT = 3.10 K , ΔT₂ = 3.10 K for calorimeter
Let be heat constant of calorimeter
Q₂ = ΔT
Heat absorbed by n-C₆H₁₄ = Q₁ - Q₂
Q₁ - Q₂ = m ΔT
number of moles of n-C₆H₁₄, n = m/M
ρ = 650 kg/m³ at 300 K
M = 86.178 g/mol
m = ρv = 650 (2x10⁻³) = 1.3 kg
n = m/M => 1.3 / 0.086178 = 15.085 moles
Q₁ - Q₂ = m ' ΔT
= (16.73 - 6.14) / (15.085 x 3.10)
= 0.22646 KJ mol⁻¹ k⁻¹