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ipn [44]
3 years ago
15

Why is it important to have the correct bond angles of the different atoms and the shape of the molecule? (20 points NEED ANSWER

ASAP)
Chemistry
1 answer:
hjlf3 years ago
5 0

It is important to have the correct bond angles of the different atoms and the shape of the molecule due to following reasons;

                  Among other properties the polarity of compounds mainly depend upon the shape and bond angles of that particular compound. For example, considering the molecule of water, we already know that it is a polar molecule with partially positive hydrogen atoms and partially negative oxygen atoms and acts as universal solvent. The bond angle in water is about 104.5° with a Bent geometry. Unlike carbon dioxide (CO₂) which has Linear structure with bond angle 180° and is non-polar in nature therefore, the bent geometry in water is responsible for the polarity.

                  Other properties which can also be predicted by predicting the bond angles along with molecular geometries are;

                                      i) Magnetism

                                      ii) Phase of matter

                                       iii) Color

                                      iv) Reactivity

                                       v) Biological activities <em>e.t.c</em>

                     

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0.040 mol / dm³. (2 sig. fig.)

<h3>Explanation</h3>

(\text{CH}_3)_3\text{N} in this question acts as a weak base. As seen in the equation in the question, (\text{CH}_3)_3\text{N} produces \text{OH}^{-} rather than \text{H}^{+} when it dissolves in water. The concentration of \text{OH}^{-} will likely be more useful than that of \text{H}^{+} for the calculations here.

Finding the value of [\text{OH}^{-}] from pH:

Assume that \text{pK}_w = 14,

\begin{array}{ll}\text{pOH} = \text{pK}_w - \text{pH} \\ \phantom{\text{pOH}} = 14 - 11.20 &\text{True only under room temperature where }\text{pK}_w = 14 \\\phantom{\text{pOH}}= 2.80\end{array}.

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\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{[(\text{CH}_3)_3\text{N}]_\text{equilibrium}} = \text{K}_b = 1.58\times 10^{-3}

Note that water isn't part of this expression.

The value of Kb is quite small. The change in (\text{CH}_3)_3\text{N} is nearly negligible once it dissolves. In other words,

[(\text{CH}_3)_3\text{N}]_\text{initial} = [(\text{CH}_3)_3\text{N}]_\text{final}.

Also, for each mole of \text{OH}^{-} produced, one mole of (\text{CH}_3)_3\text{NH}^{+} was also produced. The solution started with a small amount of either species. As a result,

[(\text{CH}_3)_3\text{NH}^{+}] = [\text{OH}^{-}] = 10^{-2.80} = 1.58\times 10^{-3}\;\text{mol}\cdot\text{dm}^{-3}.

\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{[(\text{CH}_3)_3\text{N}]_\textbf{initial}} = \text{K}_b = 1.58\times 10^{-3},

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[(\text{CH}_3)_3\text{N}]_\text{initial} =\dfrac{(1.58\times10^{-3})^{2}}{6.3\times10^{-5}} = 0.040\;\text{mol}\cdot\text{dm}^{-3}.

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