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andrezito [222]
3 years ago
6

Determine whether or not the mixing of each of the two solutions indicated below will result in a buffer.

Chemistry
1 answer:
WARRIOR [948]3 years ago
5 0
Part A

75.0 mL of 0.10 M HF; 55.0 mL of 0.15 M NaF

This combination will form a buffer.

Explanation

Here, weak acid HF and its conjugate base F- is available in the solution

Part B

150.0 mL of 0.10 M HF; 135.0 mL of 0.175 M HCl

This combination cannot form a buffer.

Explanation

Here, moles of HF = 0.15 x 0.1 = 0.015 moles

Moles of HCl = 0.135 x 0.175 = 0.023

Since HCl is a strong acid and the number of HCl is higher than HF. This prevents the dissociation of HF and the conjugate base F- will not be available in the solution

Part C

165.0 mL of 0.10 M HF; 135.0 mL of 0.050 M KOH

This combination will form a buffer.

Explanation

Moles of HF = 0.165 x 0.1 = 0.0165 moles

Moles of KOH = 0.135 x 0.05 = 0.00675 moles

Moles of KOH is not sufficient for the complete neutralization of HF. Thus weak acid HF and its conjugate base F- is available in the solution and form a buffer

Part D

125.0 mL of 0.15 M CH3NH2; 120.0 mL of 0.25 M CH3NH3Cl

This combination will form a buffer

Explanation

Here, weak acid CH3NH3+ and its conjugate base CH3NH2 is available in the solution and form a buffer

Part E

105.0 mL of 0.15 M CH3NH2; 95.0 mL of 0.10 M HCl

This combination will form a buffer

Explanation

Moles of CH3NH2 = 0.105 x 0.15 = 0.01575 moles

Moles of HCl = 0.095 x 0.1 = 0.0095 moles

Thus the HCl completely reacts with CH3NH2 and converts a part of the CH3NH2 to CH3NH3+. This results weak acid CH3NH3+ and its conjugate base CH3NH2 is in the solution and form a buffer
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Answer:

Molarity of Unknown Acid = 0.1332 M

Explanation:

Data for solving problem:

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Volume of the base in the buret (V₁)  = 21.95 mL

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It is acid base titration and  formula for this titration is as follows:

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it can be written as

M₁V₁ = M₂V₂ -------------------- equation (1)

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M₂ = 0.1517 M x 21.95 mL / 25.0 mL

M₂ = 3.3298 /25.0

M₂ = 0.1332 M

so the Molarity of Unknown acid is <u>0.1332 M</u>

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