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Ray Of Light [21]
2 years ago
5

A 0.100 M oxalic acid, HO2CCO2H, solution is titrated with 0.100 M KOH. Calculate the pH when 25.00 mL of oxalic acid solution i

s titrated with 35.00 mL of NaOH
Chemistry
1 answer:
____ [38]2 years ago
3 0

Answer:

pH = 4.09

Explanation:

molarity of oxalic acid in the solution

         = 0.1 x 25 / (25 + 35)

         = 0.0417 M

molarity of NaOH in the solution

          = 0.1 x 35 / (25 +35)

         = 0.0583 M

H2C2O4 + NaOH -------------------> NaHC2O4 + H2O

0.0417          0.0583                            0                0

0                      0.0166                         0.0417

now second acid -base titration  

NaHC2O4 + NaOH -------------------> Na2C2O4 + H2O

0.0417             0.0166                              0                0

0.0251                 0                                  0.0166         ---

now

pH = pKa2 + log [Na2C2O4 / NaHC2O4]

pH = 4.27 + log (0.0166 / 0.0251)

pH = 4.09

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Jet001 [13]

Answer:

–23000 Calories.

NOTE : The negative sign indicates that heat has been loss to the student back.

Explanation:

The following data were obtained from the question:

Mass (M) of water = 575 g

Initial temperature (T1) = 80 °C

Final temperature (T2) = 40 °C

Heat (Q) transferred =.?

Next, we shall determine the change in temperature (ΔT).

This is illustrated below:

Initial temperature (T1) = 80 °C

Final temperature (T2) = 40 °C

Change in temperature (ΔT) =?

Change in temperature (ΔT) = T2 – T1

Change in temperature (ΔT) = 40 – 80

Change in temperature (ΔT) = –40°C

Finally, we shall determine the heat transferred. This can be obtained as follow:

Mass (M) of water = 575 g

Change in temperature (ΔT) = –40°C

Specific heat capacity (C) of water = 1 Cal/g°C

Heat (Q) transferred =.?

Q = MCΔT

Q = 575 × 1 × –40

Q = –23000 Calories

NOTE : The negative sign indicates that heat has been loss to the student back.

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Explanation:

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Answer:

See explanation

Explanation:

Atomic size increases down the group due to the addition of more shells.

As more shells are added and repulsion of inner electrons become more significant, atomic size increases down the group. However, across the period, atomic size decreases due to increase in effective nuclear charge without any increase in the number of shells. This causes increased attraction between the nucleus and the outermost shell thereby decreasing the size of the atom.

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